所有图片(1)
About This Item
经验公式（希尔记法）:
C16H31P
CAS号:
分子量:
254.39
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
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方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
密度
0.939 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
CC(C)(C)P(C1CCCCC1)C2CCCCC2
InChI
1S/C16H31P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h14-15H,4-13H2,1-3H3
InChI key
MQYZHXLHUNLBQH-UHFFFAOYSA-N
一般描述
tert-Butyldicyclohexylphosphine is a bulky, electron-rich phosphine ligand.
应用
tert-Butyldicyclohexylphosphine may be used as a ligand for:
- Intermolecular palladium-catalyzed arylation of electron-rich, five-membered heterocycles by aryl chlorides.
- Palladium-catalyzed ortho-arylation of benzoic acids by aryl chloride.
警示用语：
Danger
危险声明
预防措施声明
危险分类
Pyr. Liq. 1
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Palladium-catalyzed arylation of electron-rich heterocycles with aryl chlorides.
Chiong HA and Daugulis O.
Organic Letters, 9(8), 1449-1451 (2007)
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