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![9-硼双环[3.3.1]壬烷 溶液 0.5 M in THF](/deepweb/assets/sigmaaldrich/product/structures/180/891/8b64e597-269d-4780-98b6-40889dfd06b9/640/8b64e597-269d-4780-98b6-40889dfd06b9.png)
包含
0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer
质量水平
反应适用性
reagent type: reductant
浓度
1.0 M in THF
密度
0.880 g/mL at 25 °C
官能团
ether
储存温度
2-8°C
SMILES字符串
B.C1CCOC1
InChI
1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3
InChI key
RMCYTHFAWCWRFA-UHFFFAOYSA-N
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包装
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react 1
靶器官
Central nervous system, Respiratory system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
1.4 °F - closed cup
闪点(°C)
-17 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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This paper presents a highly stereoselective synthesis of trifluoro- or difluoromethylated olefins via an S(N)2' type fluorination or reductions of gem-difluorinated vinyloxiranes. Their fluorination with HF-Py furnished trifluoromethylated allylic alcohols with exclusive E selectivity. On the other hand, their reduction
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