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方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
折射率
n20/D 1.538 (lit.)
密度
0.986 g/mL at 20 °C (lit.)
0.979 g/mL at 25 °C
官能团
phosphine
SMILES字符串
C1CCC(C1)P(C2CCCC2)C3CCCC3
InChI
1S/C15H27P/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15/h13-15H,1-12H2
InChI key
DHWBYAACHDUFAT-UHFFFAOYSA-N
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应用
- Nickel-catalyzed cycloaddition of enones and alkynes
- Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols
- Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis
- Alkenylation of imidazoles by nickel/Lewis acid catalysis
- Palladium-catalyzed Negishi cross-coupling reactions
- PHosphine-catalyzed synthesis of 6-substituted 2-pyrones
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
410.0 °F - closed cup
闪点(°C)
210 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
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