647640
氯化锆(IV)
powder, 99.99% trace metals basis
别名:
四氯化锆, 氯化锆
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关于此项目
线性分子式:
ZrCl4
化学文摘社编号:
分子量:
233.04
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-058-2
MDL number:
Assay:
99.99% trace metals basis
Grade:
anhydrous
Form:
powder
产品名称
氯化锆(IV), powder, 99.99% trace metals basis
InChI key
DUNKXUFBGCUVQW-UHFFFAOYSA-J
InChI
1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4
SMILES string
Cl[Zr](Cl)(Cl)Cl
grade
anhydrous
vapor pressure
1 mmHg ( 190 °C)
assay
99.99% trace metals basis
form
powder
reaction suitability
core: zirconium
reagent type: catalyst
Quality Level
greener alternative product characteristics
Catalysis
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sustainability
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transition temp
sublimation point 331 °C
density
2.8 g/mL at 25 °C (lit.)
application(s)
electroplating
material synthesis precursor
greener alternative category
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Application
ZrCl4 可作为各种有机合成的催化剂，如Friedel-Crafts反应、缩合反应和其他还原反应。
General description
氯化锆(IV) (ZrCl4)是一种路易斯酸催化剂，毒性低。它是一种防潮材料，在有机转化中用作催化剂。
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
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Danger
hcodes
Hazard Classifications
Met. Corr. 1 - Skin Corr. 1B
supp_hazards
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Synthesis of 2, 3-dihydroquinazolin-4 (1H)-ones catalyzed by zirconium (IV) chloride as a mild and efficient catalyst
Abdollahi-Alibeik M and Shabani E
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(10), 1163-1166 (2011)
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
Stefania Fioravanti et al.
Organic & biomolecular chemistry, 10(41), 8207-8210 (2012-09-26)
ZrCl(4) was found to be an ideal catalyst to promote aza-Henry reactions between trifluoromethyl aldimines and some nitro alkanes giving new fluorinated β-nitro amines. The reaction is strongly influenced by the CF(3) group, the yield by the alkyl chain of
Thomas A Dineen et al.
Journal of the American Chemical Society, 128(50), 16406-16409 (2006-12-15)
Two protocols for the transamidation of primary amides with primary and secondary amines, forming secondary and tertiary amides, respectively, are described. Both processes employ N,N-dialkylformamide dimethyl acetals for primary amide activation, producing N'-acyl-N,N-dialkylformamidines as intermediates, as widely documented in the
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