640360
双（乙腈）（1,5-环辛二烯）铑 (I) 四氟硼酸盐
solid
别名:
[Rh(cod)(MeCN)2]BF4
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选择尺寸
关于此项目
经验公式（希尔记法）:
C12H18BF4N2Rh
化学文摘社编号:
分子量:
379.99
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
双（乙腈）（1,5-环辛二烯）铑 (I) 四氟硼酸盐,
SMILES string
[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
InChI
1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
InChI key
KSMAFOANQHYEJG-SUESZSCISA-N
form
solid
reaction suitability
core: rhodium, reagent type: catalyst
Quality Level
Application
双（乙腈）（1,5-环辛二烯）四氟硼酸铑（I）[Rh(cod)(MeCN)2]BF4 可作为催化剂用于芳基碘和溴与四乙氧基硅烷的铑（I）催化甲硅烷基化反应 以形成芳基硅烷，例如（4-溴苯基）三乙氧基硅烷和4-（三乙氧基甲硅烷基）苯乙酮。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Periodic mesoporous organosilica containing ionic bis-aryl-imidazolium entities: Heterogeneous precursors for silica-hybrid-supported NHC complexes.
Nguyen TP, et al.
Journal of Materials Chemistry, 19(24), 4164-4171 (2009)
Pingping Tang et al.
Tetrahedron, 67(24), 4449-4454 (2011-06-22)
A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag(2)O as readily available, inexpensive silver source, which can be recovered.
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