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Merck
CN

638102

Sigma-Aldrich

4,4′-双(三乙氧基甲硅烷)-1,1′-联苯

≥90% (VPCC)

别名:

4,4′-双(三乙氧基甲硅烷)联苯

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About This Item

线性分子式:
[-C6H4Si(OC2H5)3]2
分子量:
478.73
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

≥90% (VPCC)

沸点

203-206 °C/0.3 mmHg (lit.)

密度

1.047 g/mL at 25 °C (lit.)

SMILES字符串

CCO[Si](OCC)(OCC)c1ccc(cc1)-c2ccc(cc2)[Si](OCC)(OCC)OCC

InChI

1S/C24H38O6Si2/c1-7-25-31(26-8-2,27-9-3)23-17-13-21(14-18-23)22-15-19-24(20-16-22)32(28-10-4,29-11-5)30-12-6/h13-20H,7-12H2,1-6H3

InChI key

KENDGHJJHKCUNB-UHFFFAOYSA-N

应用

4,4′-二(三乙氧基)-1,1′′-联苯(BTESB) 可以用作测定螺旋二氧化硅纳米管手性的指示剂。

BTESB可用作制备以下物质的前体:
  • 以 3-氨基丙基三甲氧硅烷为助结构导向剂制备的4, 4′-联苯-二氧化硅螺旋纳米管和纳米带 。
  • 通过与线型脂肪族二醇缩合形成的联苯桥连的烷氧基硅烷交联的聚烷氧基硅烷。
  • 通过溶胶-凝胶法合成的联苯桥连的硅倍半氧烷。

在 Pd 催化的交叉偶联反应中具有反应活性的硅基亲核试剂。

危险声明

危险分类

Aquatic Chronic 4

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

>230.0 °F - closed cup

闪点(°C)

> 110 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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