质量水平
检测方案
97%
折射率
n20/D 1.472 (lit.)
bp
78-80 °C/18 mmHg (lit.)
密度
0.902 g/mL at 25 °C (lit.)
SMILES字符串
CN[C@@H]1CCCC[C@H]1NC
InChI
1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1
InChI key
JRHPOFJADXHYBR-HTQZYQBOSA-N
一般描述
反式-N,N′-二甲基环丙烷-1,2-二胺是一种配体，用于促进酰胺的 N-烯基化和N-烷化反应。
应用
反式- N,N′- 二甲基环己烷-1,2-二胺可用作铜催化 C-N 偶联反应合成下列产物的配体：
- 从 NH 亚砜肟和乙烯基溴获得的乙烯基亚砜亚胺
- 通过 2-取代吡啶和芳基卤化物反应获得的 N- 芳基吡啶酮
- 胺与芳基碘化物/芳基溴化物反应获得的 N- 芳基胺
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
WGK
WGK 3
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Copper-catalyzed one-pot N-alkenylation and N-alkylation of amides: an efficient synthesis of substituted 2, 3-dihydropyrroles
Zhou, Xiaobo and Zhang, et al.
Tetrahedron Letters, 48, 7236-7239 (2007)
"A General Copper-Promoted Coupling of Sulfoximines with Vinyl Bromides"
Dehli.RJ and Bolm C
Advanced Synthesis & Catalysis, 347(2-3), 239-242 (2005)
"Cu-catalyzed Goldberg and Ullmann reactions of aryl halides using chelating N-and O-based ligands"
Altman AR and Buchwald LS
Nature Protocols, 2(10), 2474-2479 (2007)
Regioselective copper-catalyzed N (1)-(hetero) arylation of protected histidine
Sharma, et al.
Organic & Biomolecular Chemistry, 14, 8937-8941 (2016)
"An improved Ullmann?Ukita?Buchwald?Li conditions for CuI-catalyzed coupling reaction of 2-pyridones with aryl halides"
Tetrahedron, 61(11), 2931-2939 (2005)
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