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检测方案
97%
形式
solid
mp
139-143 °C (lit.)
SMILES字符串
O=Cc1cccc2[nH]ccc12
InChI
1S/C9H7NO/c11-6-7-2-1-3-9-8(7)4-5-10-9/h1-6,10H
InChI key
JFDDFGLNZWNJTK-UHFFFAOYSA-N
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一般描述
Indole-4-carboxaldehyde participates in the synthesis of arcyriacyanin A. Synthesis of 4-indole-4-carboxaldehyde has been reported. Intramolecular Friedel-Crafts (FC) acylation of indole-4-carboxaldehyde has been reported.
应用
- reactant in Biginelli reaction
- reactant in synthesis of aurora kinase A inhibitors
- reactant in preparation of antitumor agents
- reactant in intramolecular Friedel-Crafts acylation
- reactant in preparation of inhibitors of cell division in E. coli
- reactant in synthesis of Hantzsch pyridine-containing Schiff bases
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
Synthesis of Fused 4, 5-Disubstituted Indole Ring Systems by Intramolecular Friedel-Crafts Acylation of 4-Substituted Indoles.
Fillion E and Dumas AM.
The Journal of Organic Chemistry, 73(7), 2920-2923 (2008)
Synthesis of (-)-chanoclavine I.
Kardos N and Genet J-P.
Tetrahedron Asymmetry, 5(8), 1525-1533 (1994)
Total syntheses of clavine alkaloids by an intramolecular nitrone-olefin cycloaddition reaction.
Oppolzer W, et al.
Tetrahedron, 39(22), 3695-3705 (1983)
George A Kraus et al.
Organic letters, 10(14), 3061-3063 (2008-06-25)
The reaction of (2-aminobenzyl) triphenylphosphonium bromide with aromatic aldehydes or alpha,beta-unsaturated aldehydes under microwave-assisted conditions constitutes a new synthesis of 2-substituted indoles in high yields (81-97%) in a one-pot reaction. The adduct from indole-4-carboxaldehyde was an advanced intermediate in the
A New Synthesis method of indole-4-carboxaldehyde.
Wu Y-M, et al.
He Cheng Hua Xue / Chinese Journal of Synthetic Chemistry, 12, 333-335 (2004)
商品
Friedel-Crafts acylation with Lewis acid catalysts forms monoacylated products via electrophilic aromatic substitution of arenes.
傅-克酰基化反应是一种芳烃与酰氯或酸酐使用强路易斯酸催化剂的反应。该反应通过亲电芳族取代进行，形成单酰化产物。
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