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检测方案
95%
折射率
n20/D 1.6070 (lit.)
bp
107-109 °C/12 mmHg (lit.)
密度
1.589 g/mL at 25 °C (lit.)
SMILES字符串
CNc1ccccc1Br
InChI
1S/C7H8BrN/c1-9-7-5-3-2-4-6(7)8/h2-5,9H,1H3
InChI key
SMVIAQFTVWDWDS-UHFFFAOYSA-N
一般描述
2-Bromo-N-methylaniline can be synthesized via the reduction of 2-bromoformylanilide.
应用
2-Bromo-N-methylaniline can be used to synthesize benzimidazole derivatives, via one pot N-arylation of amides/cyclic amides in the presence of copper iodide nanoparticles. It can also be used in the synthesis of alkyltelluro-substituted aromatic amines, which can show radical trapping ability.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral
WGK
WGK 2
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
"Nanoparticle mediated organic synthesis (NAMO-synthesis): CuI-NP catalyzed ligand free amidation of aryl halides"
Kumar A and Bishnoi KA
Royal Society of Chemistry Advances, 4(78), 41631- 41635 (2014)
Poon F-J, et al.
Chemistry?A European Journal , 22(36), 12891-12903 (2016)
"Syntheses of 2-Unsubstituted 1H-1, 3-Benzazaphospholes from N-Formyl-2-bromoanilides"
Ghalib M, et al.
Heteroatom Chem., 4(78), 452-459 (2013)
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