推荐产品
形式
suspension
反应适用性
reagent type: reductant
浓度
~3.5 M in THF/toluene
密度
0.89 g/mL at 20 °C
储存温度
2-8°C
SMILES字符串
[Li+].[AlH4-]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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应用
反应物或试剂用于：
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
- 由油酸制备热塑性聚酯聚酰胺
- 锂聚合物电池
- 宝石-二氟亚甲基衍生物的加氢脱氟
- 不对称羟醛反应
- 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 2 - STOT SE 3 - Water-react 1
靶器官
Central nervous system, Respiratory system
补充剂危害
WGK
WGK 3
闪点(°F)
-4.0 °F
闪点(°C)
-20 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Mitsuteru Numazawa et al.
Chemical & pharmaceutical bulletin, 54(4), 554-556 (2006-04-06)
Reduction of a double bond at C-1 of 1,4-dien-3-one steroids 7 and 8 with LiAl2H4 in THF or NaB2H4 in MeOH and H2O gave stereospecifically [1alpha-2H]-labeled 4-en-3-one steroids 9 and 10, respectively. When the deuterated solvents, MeO2H and 2H2O, were
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and
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