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质量水平
检测方案
≥95.0% (sum of enantiomers, GC)
旋光性
[α]20/D −18±3°, neat
折射率
n20/D 1.4615 (lit.)
n20/D 1.462
bp
198 °C (lit.)
密度
0.862 g/mL at 20 °C (lit.)
SMILES字符串
C\C(C)=C\CC[C@@](C)(O)C=C
InChI
1S/C10H18O/c1-5-10(4,11)8-6-7-9(2)3/h5,7,11H,1,6,8H2,2-4H3/t10-/m0/s1
InChI key
CDOSHBSSFJOMGT-JTQLQIEISA-N
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一般描述
(-)-芳樟醇是一种单萜化合物，主要存在于许多精油中。它具有抗伤害和抗炎活性。
应用
(-)-芳樟醇可用作反应物参与：
- 通过非对映选择性自由基级联环化，对映选择性地制备蛇孢假壳素二倍半萜
- 通过 (-)-里哪醇O-三乙基甲硅烷醚进行(-)-5,6-二氢霉素B 的全合成；
- pladienolide B 类似物的全合成
警示用语：
Warning
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of a pladienolide B analogue with the fully functionalized core structure
Mu?ller S, et al.
Organic Letters, 13(15), 3940-3943 (2011)
Amy L Parachnowitsch et al.
Plant signaling & behavior, 8(1), e22704-e22704 (2012-12-12)
Natural selection is thought to have shaped the evolution of floral scent; however, unlike other floral characters, we have a rudimentary knowledge of how phenotypic selection acts on scent. We found that floral scent was under stronger selection than corolla
Nan Zhang et al.
Phytomedicine : international journal of phytotherapy and phytopharmacology, 23(14), 1727-1734 (2016-12-04)
Essential oil from Cananga odorata (ylang-ylang essential oil, YYO) is usually used in reducing blood pressure, improving cognitive functioning in aromatherapy in human. Few reports showed its effect on anxiety behaviors. To investigate the anxiolytic effects of YYO exposure on
(-)-Linalool produces antinociception in two experimental models of pain.
Peana AT, et al.
European Journal of Pharmacology, 460(1), 37-41 (2003)
Enantioselective synthesis of an ophiobolin sesterterpene via a programmed radical cascade
Brill ZG, et al.
Science (New York, N.Y.), 352(6289), 1078-1082 (2016)
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