推荐产品
质量水平
反应适用性
core: boron
reagent type: Lewis acid
reagent type: catalyst
浓度
13-15% boron trifluoride
密度
0.859 g/mL at 25 °C
官能团
hydroxyl
SMILES字符串
CO.FB(F)F
InChI
1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
InChI key
JBXYCUKPDAAYAS-UHFFFAOYSA-N
一般描述
BF3-MeOH溶液是一种路易斯酸-碱复合物，在有机合成中用作多功能的试剂和催化剂。
应用
三氟化硼 - 甲醇络合物溶液可用于花青染料的乙酰化胺的脱保护，以形成具有游离氨基的产物。它可用于将含硫氨基磷酸酯转化为相应的磷酸甲酯
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1
靶器官
Eyes,Central nervous system, Kidney
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
60.8 °F - closed cup
闪点(°C)
16 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Methanolysis of phosphoramidates with boron trifluoride-methanol complex.
Ryu S
The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)
Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.
Miltsov S
Tetrahedron Letters, 44(11), 2301-2303 (2003)
C Hue-Beauvais et al.
Journal of animal science, 93(4), 1641-1655 (2015-05-29)
Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.
Leila Nejadsadeghi et al.
Molecular biology reports, 42(2), 363-372 (2014-10-01)
Plant cells often increase cold tolerance by reprogramming their genes expression which results in adjusted metabolic alternations, a process enhanced under cold acclimation. In present study, we assessed the changes of membrane fatty acid compositions along with physio-biochemical indices like
Shulin Xiang et al.
Journal of pineal research, 59(1), 60-69 (2015-04-11)
Chemotherapeutic resistance, particularly to doxorubicin (Dox), represents a major impediment to successfully treating breast cancer and is linked to elevated tumor metabolism and tumor over-expression and/or activation of various families of receptor- and non-receptor-associated tyrosine kinases. Disruption of circadian time
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