61139
铜
≥99.0%, turnings, purum p.a.
别名:
Cu
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关于此项目
经验公式（希尔记法）:
Cu
化学文摘社编号:
分子量:
63.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12141711
EC Number:
231-159-6
MDL number:
产品名称
铜, turnings, purum p.a., ≥99.0%
InChI key
RYGMFSIKBFXOCR-UHFFFAOYSA-N
InChI
1S/Cu
SMILES string
[Cu]
grade
purum p.a.
assay
≥99.0%
quality
turnings
reaction suitability
core: copper
reagent type: catalyst
resistivity
1.673 μΩ-cm, 20°C
turnings L
~0.5 cm
bp
2567 °C (lit.)
mp
1083.4 °C (lit.)
density
8.94 g/mL at 25 °C (lit.)
cation traces
Al: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Fe: ≤200 mg/kg
Mg: ≤50 mg/kg
Mn: ≤50 mg/kg
Ni: ≤50 mg/kg
Pb: ≤100 mg/kg
Zn: ≤200 mg/kg
Quality Level
Application
Copper turnings are used to synthesize inorganic salts and organometallic complexes and catalysts that can be employed in a variety of synthetic transformations. It is useful in:
- Synthesis of polynitro[60]fullerene.
- Copper-catalyzed azide-alkyne Huisgen cycloaddition (click reaction) to synthesize 5-membered heterocycles.
- Trifluoromethylation of heteroaromatic compounds.
- Preparation of electrolyte for all-copper hybrid flow batteries.
General description
Copper turnings are a form of copper metal that has been specifically cut to have a high surface area. This form of copper is particularly useful because it provides a greater contact area for reagents to interact with which can help speed up reactions and increase yields.
存储类别
13 - Non Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Copper catalysis in organic synthesis.
Sherry R C.
Beilstein Journal of Organic Chemistry, 11, 2252?2253-2252?2253 (2015)
Structural and thermal properties of the alkaline cuprate KCuO2
Giorgio A. Costa, Elena Kaiser
Thermochimica Acta, 591-598 (1995)
Encyclopedia of Inorganic and Bioinorganic Chemistry (2011)
Evaluation of electrode materials for all-copper hybrid flow batteries.
Leung P, et al.
Journal of Power Sources, 310, 1-11 (2016)
Three-component coupling of alkynes, Baylis?Hillman adducts and sodium azide: A new synthesis of substituted triazoles.
Chandrasekhar S, et al.
Tetrahedron Letters, 47(18), 3059-3063 (2006)
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