595721
(R)-(+)-3,3′-二溴-1,1′-二-2-萘醇
97%
别名:
(R)-3,3′-Dibromo-1,1′-bi-2-naphthol, (R)-3,3′-Dibromo-[1,1′-Binaphthalene]-2,2′-diol, (R)-Dibromo-1,1′-Bi-2,2′-naphthol, (R)-Dibromo-1,1′-Binaphthalene-2,2′-diol, (R)-Dibromo-1,1-Binaphthol, (R)-Dibromo-BINOL, (R)-Dibromo-bi-2-naphthol
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所有图片(2)
About This Item
经验公式（希尔记法）:
C20H12Br2O2
CAS号:
分子量:
444.12
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
97%
形式
solid
mp
256-260 °C
InChI
1S/C20H12Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h1-10,23-24H
InChI key
BRTBEAXHUYEXSY-UHFFFAOYSA-N
应用
(R)-(+)-3,3′-Dibromo-1,1′-bi-2-naphthol reacts with zirconium(IV) tert-butoxide to form a chiral zirconium complex, which can efficiently catalyze:
- anti-selective catalytic asymmetric aldol reactions of silyl enol ethers with aldehydes
- asymmetric intramolecular [3+2] cycloaddition of hydrazone/olefins
警示用语：
Warning
危险声明
预防措施声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Asymmetric intramolecular [3+2] cycloaddition reactions of acylhydrazones/olefins using a chiral zirconium catalyst.
Kobayashi S, et al.
Journal of the American Chemical Society, 124(46), 13678-13679 (2002)
Highly anti-selective catalytic asymmetric aldol reactions.
Ishitani H, et al.
Journal of the American Chemical Society, 122(22), 5403-5404 (2000)
商品
We present an article concerning BINOL and Derivatives.
我们展示了一篇有关BINOL及其衍生物的文章。
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