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Merck
CN

594261

Sigma-Aldrich

5-溴异喹啉

98%

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About This Item

经验公式(希尔记法):
C9H6BrN
CAS号:
分子量:
208.05
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

98%

mp

83-87 °C (lit.)

官能团

bromo

SMILES字符串

Brc1cccc2cnccc12

InChI

1S/C9H6BrN/c10-9-3-1-2-7-6-11-5-4-8(7)9/h1-6H

InChI key

CYJZJGYYTFQQBY-UHFFFAOYSA-N

应用

用于钯催化的氨甲基化和胺化反应的原料。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

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Qilong Shen et al.
Journal of the American Chemical Society, 128(31), 10028-10029 (2006-08-03)
A mild, palladium-catalyzed coupling of aryl halides with ammonia or lithium amide to form primary arylamines as the major product is described. These reactions occurred with excellent selectivity for formation of the primary arylamine over formation of the diarylamine (9.5:1
Gary A Molander et al.
Organic letters, 9(8), 1597-1600 (2007-03-21)
[reaction: see text] The Suzuki-Miyaura cross-coupling reaction of N,N-dialkylaminomethyltrifluoroborates with aryl halides allows the construction of an aminomethyl aryl linkage through a disconnection based on dissonant reactivity patterns. A variety of these aminomethyltrifluoroborate substrates were prepared in good to excellent

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