593702
氢化铝锂 溶液
2.0 M in THF
别名:
LAH, 丙氨酸锂, 四氢铝酸锂
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
LiAlH4
化学文摘社编号:
分子量:
37.95
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
InChI
1S/Al.Li.4H/q-1;+1;;;;
SMILES string
[Li+].[AlH4-]
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
reaction suitability
reagent type: reductant
concentration
2.0 M in THF
density
0.906 g/mL at 25 °C
storage temp.
2-30°C
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
反应物或试剂用于：
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
- 由油酸制备热塑性聚酯聚酰胺
- 锂聚合物电池
- 宝石-二氟亚甲基衍生物的加氢脱氟
- 不对称羟醛反应
- 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成
LAH 是许多不同还原反应的强还原剂，例如酮类与醇类的还原反应
Packaging
建议将 25 mL Sure/密封™瓶作为一次性使用瓶。重复穿刺可能导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react. 1
法规信息
监管及禁止进口产品
此项目有
Sonja Stanković et al.
Organic & biomolecular chemistry, 8(19), 4266-4273 (2010-08-05)
A new synthetic protocol for the LiAlH(4)-promoted reduction of non-activated aziridines under microwave conditions was developed. Thus, ring opening of 2-(acetoxymethyl)aziridines provided the corresponding beta-amino alcohols, which were then used as eligible substrates in the synthesis of 5-methylmorpholin-2-ones via condensation
Mitsuteru Numazawa et al.
Chemical & pharmaceutical bulletin, 54(4), 554-556 (2006-04-06)
Reduction of a double bond at C-1 of 1,4-dien-3-one steroids 7 and 8 with LiAl2H4 in THF or NaB2H4 in MeOH and H2O gave stereospecifically [1alpha-2H]-labeled 4-en-3-one steroids 9 and 10, respectively. When the deuterated solvents, MeO2H and 2H2O, were
Hideki Hashizume et al.
The Journal of antibiotics, 57(1), 52-58 (2004-03-23)
Planar structures of tripropeptins (TPPs) were elucidated by spectroscopic studies including various NMR measurements. Stereochemistry of constituent amino acids of tripropeptin C (TPPC) (3) was identified by marfey's method except hydroxyproline which was determined by studies of NMR and CD
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持