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Merck
CN

593702

Sigma-Aldrich

氢化铝锂 溶液

2.0 M in THF

别名:

LAH, 丙氨酸锂, 四氢铝酸锂

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About This Item

线性分子式:
LiAlH4
CAS号:
分子量:
37.95
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.22

质量水平

反应适用性

reagent type: reductant

浓度

2.0 M in THF

密度

0.906 g/mL at 25 °C

储存温度

2-30°C

SMILES字符串

[Li+].[AlH4-]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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应用

反应物或试剂用于:
  • 由油酸制备热塑性聚酯聚酰胺
  • 锂聚合物电池
  • 宝石-二氟亚甲基衍生物的加氢脱氟
  • 不对称羟醛反应
  • 具有吸氢/解吸特性的 Li-Al-N-H 复合材料的合成

LAH 是许多不同还原反应的强还原剂,例如酮类与醇类的还原反应

包装

建议将 25 mL Sure/密封瓶作为一次性使用瓶。重复穿刺可能导致产品性能下降。

法律信息

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1

靶器官

Central nervous system, Respiratory system

补充剂危害

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

闪点(°F)

-13.0 °F - closed cup

闪点(°C)

-25 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as
Mitsuteru Numazawa et al.
Chemical & pharmaceutical bulletin, 54(4), 554-556 (2006-04-06)
Reduction of a double bond at C-1 of 1,4-dien-3-one steroids 7 and 8 with LiAl2H4 in THF or NaB2H4 in MeOH and H2O gave stereospecifically [1alpha-2H]-labeled 4-en-3-one steroids 9 and 10, respectively. When the deuterated solvents, MeO2H and 2H2O, were
Hideki Hashizume et al.
The Journal of antibiotics, 57(1), 52-58 (2004-03-23)
Planar structures of tripropeptins (TPPs) were elucidated by spectroscopic studies including various NMR measurements. Stereochemistry of constituent amino acids of tripropeptin C (TPPC) (3) was identified by marfey's method except hydroxyproline which was determined by studies of NMR and CD
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and

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