所有图片(1)
别名:
(4-tert-Butylphenyl)ethyne, 1-(1,1-Dimethylethyl)-4-ethynylbenzene, 1-Ethynyl-4-(t-Butyl)benzene, 1-Ethynyl-4-tert-butylbenzene, 1-tert-Butyl-4-ethynylbenzene, 4-tert-Butyl-1-ethynylbenzene, p-tert-Butylphenylacetylene
线性分子式:
(CH3)3C6H4C≡CH
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质量水平
检测方案
96%
形式
liquid
bp
70 °C/2 mmHg (lit.)
密度
0.877 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)c1ccc(cc1)C#C
InChI
1S/C12H14/c1-5-10-6-8-11(9-7-10)12(2,3)4/h1,6-9H,2-4H3
InChI key
ZSYQVVKVKBVHIL-UHFFFAOYSA-N
一般描述
由 4-叔丁基苯乙烯合成 4-叔丁基苯基乙炔。
应用
4-叔丁基苯基乙炔可用于合成以下物质：
- 1,6-双（4-叔丁基苯基）六-1,5-二炔-3,4-二酮
- 通过与 4,4'，5,5'-四碘二苯并-24-皇冠-8-醚发生 Sonogashira 偶联反应形成 4,4'，5,5'-四（4-叔丁基苯基）二苯并-24-冠-8-醚
- 经钯催化与 4-（叔丁基二甲基甲硅烷氧基）碘苯发生偶联反应合成 1-（4-叔丁基苯基）-2-（4-叔丁基二甲基甲硅烷氧基苯基）乙炔
警示用语：
Warning
危险声明
预防措施声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1
WGK
WGK 3
闪点(°F)
180.0 °F
闪点(°C)
82.2 °C
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
"An efficient synthesis of 4, 4', 5, 5'-tetraiododibenzo-24-crown-8 and its highly conjugated derivatives"
Pak.JJ, et al.
Tetrahedron Letters, 47(02), 233-237 (2006)
Atsushi Tamura et al.
Beilstein journal of organic chemistry, 12, 2883-2892 (2017-02-02)
Cyclodextrin (CD)-threaded polyrotaxanes (PRXs) with reactive functional groups at the terminals of the axle polymers are attractive candidates for the design of supramolecular materials. Herein, we describe a novel and simple synthetic method for end-reactive PRXs using bis(2-amino-3-phenylpropyl) poly(ethylene glycol)
Li-Jing Han et al.
Dalton transactions (Cambridge, England : 2003), 49(24), 8347-8353 (2020-06-11)
A series of dinuclear platinum(ii) alkynyl complexes [Pt2L2(C[triple bond, length as m-dash]CC6H4R-4)4] (R = H 1, CH32, But3) and unusual tetranuclear Pt(ii)-Ag(i) clusters [Pt2Ag2L(C[triple bond, length as m-dash]CC6H4R-4)6] (R = H, 4; CH3, 5; But, 6), together with novel polymer
"Synthesis and gas permeation properties of poly (diphenylacetylenes) having bulky alkyl/silyl and hydroxy groups"
Hu Y, et al.
Journal of Membrane Science , 282(01), 423-429 (2006)
"NIR chromophores from small acetylenic building blocks: a Diels?Alder approach to octaalkynylphthalocyanines"
Faust R and Mitzel F
Journal of the Chemical Society. Perkin Transactions 1, (22), 3746-3751 (2000)
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