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检测方案
99%
形式
solid
bp
208 °C (lit.)
mp
37-41 °C (lit.)
密度
1.124 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)CC(=C)C(=O)OC
InChI
1S/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3
InChI key
ZWWQRMFIZFPUAA-UHFFFAOYSA-N
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一般描述
衣康酸二甲酯可以通过衣康酸的酯化反应进行合成。
应用
衣康酸二甲酯可用于铑催化的(S)-二甲基-2-甲基琥珀酸酯 和(R)-甲基琥珀酸二甲酯的不对称氢化反应。
警示用语：
Warning
危险声明
危险分类
Skin Irrit. 2 - Skin Sens. 1B
WGK
WGK 3
闪点(°F)
212.0 °F
闪点(°C)
100 °C
个人防护装备
Eyeshields, Gloves, type N95 (US)
?Modification of poly(propylene) through grafting with dimethyl
itaconate in solution?
itaconate in solution?
Yazdani-Pedram M, et al.
Macromolecular Chemistry and Physics, 199(11), 2495- 2500 (1998)
Yepin Zhao et al.
Advanced materials (Deerfield Beach, Fla.), 32(17), e1907769-e1907769 (2020-03-10)
Intrinsically, detrimental defects accumulating at the surface and grain boundaries limit both the performance and stability of perovskite solar cells. Small molecules and bulkier polymers with functional groups are utilized to passivate these ionic defects but usually suffer from volatility
"Catalytic asymmetric hydrogenation of dimethyl itaconate with trans-chelating chiral diphosphine ligands TRAP-rhodium complexes"
Kuwano R, et al.
Tetrahedron Asymmetry, 6(10), 2521- 2526 (1995)
?New ferrocenyl ligands with broad applications in asymmetric catalysis?
Lotz M, et al.
Angewandte Chemie (International Edition in English), 41(24), 4708-4711 (2002)
Vittoria Chimisso et al.
Langmuir : the ACS journal of surfaces and colloids, 35(41), 13413-13420 (2019-10-05)
Poly(N-vinylcaprolactam-co-itaconate) (P(VCL-co-IADME) microgels were synthesized varying the molar ratio between VCL and IADME via free radical precipitation polymerization in the presence of quaternary ammonium surfactant. In order to determine the effect of the divalent metal ions on the structure and
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