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Merck
CN
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文件

安全信息

592285

Sigma-Aldrich

三环己基磷 溶液

1 M in toluene

别名:

NSC 158657, PCy3

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About This Item

线性分子式:
(C6H11)3P
CAS号:
2622-14-2
分子量:
280.43
Beilstein:
957171
MDL编号:
MFCD00003853
UNSPSC代码:
12350000
PubChem化学物质编号:
24881380
NACRES:
NA.22

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

浓度

1 M in toluene

密度

0.901 g/mL at 25 °C

官能团

phosphine

SMILES字符串

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3

InChI

1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2

InChI key

WLPUWLXVBWGYMZ-UHFFFAOYSA-N

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应用

Catalyst for:
  • Carbonylative Suzuki-coupling of benzyl halides with potassium aryltrifluoroborates
  • Suzuki-Miyaura reactions of aryl sulfonates / halides with arylboronic acids
  • Synthesis of an acromelic acid A analog based 11C-labeled PET tracer
  • Synthesis of (-)-Exiguolide and its analogues
  • Allylation of zinc enolates

警示用语：

Danger

危险分类

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Adrian Tlahuext-Aca et al.
Dalton transactions (Cambridge, England : 2003), 43(42), 15997-16005 (2014-09-19)
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic system shows low to moderate tolerance for fluoro-, trifluoromethyl-
Sebastijan Kovačič et al.
Macromolecular rapid communications, 36(17), 1605-1611 (2015-07-15)
Metal-organic frameworks (MOFs) nanoparticles in combination with a nonionic surfactant (Pluronic L-121) are used to stabilize dicyclopentadiene (DCPD)-in-water high internal phase emulsions (HIPEs). The resulting HIPEs containing the MIL-100(Fe) nanoparticles (MIL: Materials of Institut Lavoisier) at the interface between the

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