质量水平
检测方案
97%
反应适用性
core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization
mp
153 °C (dec.)
储存温度
2-8°C
SMILES字符串
C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]
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应用
第一个被广泛用于有机合成的复分解催化剂。适用于各种反应条件下末端烯烃的无环二烯复分解聚合（ADMET）、应变环烯烃的开环复分解聚合（ROMP）、开环复分解（ROM）、烯烃交叉复分解（CM）和关环复分解（RCM）。
了解我们的复分解催化剂的更多信息。
了解我们的复分解催化剂的更多信息。
法律信息
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG
警示用语：
Warning
危险声明
危险分类
Flam. Sol. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Brummer, O.; Ruckert, a.; Blechert, S.
Chemistry (Weinheim An Der Bergstrasse, Germany), 3, 441-441 (1997)
Brzezinska, K.; Wolfe, P. S.
Macromolecular Chemistry and Physics, 197, 2065-2065 (1996)
Michaut, M.; Parrain, J.-L.; Santelli, M.
Chemical Communications (Cambridge, England), 2567-2567 (1998)
Charvet, R.: Novak, B. M.
Macromolecules, 34, 7680-7680 (2001)
Young-Woo Kim et al.
Nature protocols, 6(6), 761-771 (2011-06-04)
This protocol provides a detailed procedure for the preparation of stapled α-helical peptides, which have proven their potential as useful molecular probes and as next-generation therapeutics. Two crucial features of this protocol are (i) the construction of peptide substrates containing
商品
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
相关内容
Research in the Grubbs group has centered on the development and application of a suite of highly active, selective, and bench stable ruthenium alkylidene complexes capable of catalyzing versatile olefin metatheses.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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