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Merck
CN

574082

Sigma-Aldrich

乙酰丙酮铬

99.99% trace metals basis

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别名:
2,4-戊二酮铬, Cr(acac)3
线性分子式:
Cr(C5H7O2)3
CAS号:
分子量:
349.32
Beilstein:
4148971
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.23

检测方案

99.99% trace metals basis

形式

solid

反应适用性

core: chromium

bp

340 °C (lit.)

mp

210 °C (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[Cr](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Cr/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

JWORPXLMBPOPPU-LNTINUHCSA-K

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一般描述

乙酰丙酮铬(III)为酸性戊胺铬(111)盐,是一种结晶材料,可通过用乙酰丙酮处理沉淀的水合氧化铬(III)制备。

应用

乙酰丙酮铬(III)可用作活性部位,形成氧化还原体系,制造液流电池。也可用作基于氮化铬金属涂层的前体。

分析说明

用于对在其存在下形成的固体聚氨酯进行表面改性。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 2

闪点(°F)

>392.0 °F

闪点(°C)

> 200 °C

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Chromium (III) acetylacetonate
Fernelius WC, et al.
Inorganic Syntheses, 5, 130-131 (1957)
Plasma assisted metal-organic chemical vapor deposition of hard chromium nitride thin film coatings using chromium (III) acetylacetonate as the precursor
Dasgupta A, et al.
Materials Science & Engineering. A, Structural Materials : Properties, Microstructure and Processing, 374(1-2), 362-368 (2004)
Non-aqueous chromium acetylacetonate electrolyte for redox flow batteries
Liu Q, et al.
Electrochemical Communications, 12(11), 1634-1637 (2010)
Yanfang Li et al.
Dalton transactions (Cambridge, England : 2003), 41(13), 3807-3816 (2012-02-24)
Biscyclometalated iridium(III) complexes with an ancillary acetylacetone ligand, Ir(L)(2)(acac), (L = 2-(benzo[b]thiophen-2-yl)pyridine (btp), 1-phenylisoquinoline (piq), 2-phenylbenzothiazole (bt), 2-phenylpyridine (ppy), acac = deprotonated acetylacetone), demonstrate spectroscopic changes in their UV-Vis absorption and luminescent emission under acidic conditions. Such changes were found
David N Paglia et al.
Journal of orthopaedic research : official publication of the Orthopaedic Research Society, 30(12), 1971-1978 (2012-06-02)
This study quantified the effects of local intramedullary delivery of an organic vanadium salt, which may act as an insulin-mimetic on fracture healing. Using a BB Wistar rat femoral fracture model, local vanadyl acetylacetonate (VAC) was delivered to the fracture

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