所有图片(1)
About This Item
线性分子式:
H3CCH=CHB(OH)2
CAS号:
分子量:
85.90
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
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方案
≥95.0%
组成
trans isomer, ≤10%
mp
65-70 °C (lit.)
储存温度
−20°C
SMILES字符串
C\C=C/B(O)O
InChI
1S/C3H7BO2/c1-2-3-4(5)6/h2-3,5-6H,1H3/b3-2-
InChI key
CBMCZKMIOZYAHS-IHWYPQMZSA-N
应用
cis-1-Propen-1-ylboronic acid can be used:
- As an intermediate in the preparation of furan-2-yl analog of salvinorin A, a psychoactive natural product.
- To synthesize antibacterial polyoxygenated dibenzofuran derivatives from phloroglucinol.
- As a substrate in the palladium-catalyzed cis-vinyl arenes synthesis by reacting with various aryl chlorides.
其他说明
含有不定量的酸酐
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
219.2 °F - closed cup
闪点(°C)
104.00 °C - closed cup
个人防护装备
Eyeshields, Gloves
Synthesis and antibacterial activity of new symmetric polyoxygenated dibenzofurans
Oramas-Royo S, et al.
European Journal of Medicinal Chemistry, 141(9), 178-187 (2017)
Palladium-catalyzed cross-coupling of aryl chlorides with alkenylboronic acids with low E/Z isomerization
Thimmaiah M, et al.
Tetrahedron Letters, 49(39), 5605-5607 (2008)
Kimberly M Lovell et al.
Bioorganic & medicinal chemistry, 20(9), 3100-3110 (2012-04-03)
Modification of the furan ring of salvinorin A (1), the main active component of Salvia divinorum, has resulted in novel neoclerodane diterpenes with opioid receptor affinity and activity. Conversion of the furan ring to an aldehyde at the C-12 position
Ioan-Adrian Stoian et al.
Biosensors & bioelectronics, 155, 112098-112098 (2020-02-25)
A highly selective and sensitive molecularly imprinted polymer (MIP)-based electrochemical sensor was fabricated for the determination of azithromycin, a broad-spectrum macrolide antibiotic, from various biological samples (urine, tears, plasma). The reversible boronate ester bond-mediated, thin (~75 nm) MIP-based biomimetic recognition layer
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