等级
anhydrous
质量水平
同位素纯度
≥99.8 atom % D
检测方案
≥99% (CP)
形式
liquid
expl. lim.
5.5-36.5 % (lit.)
技术
NMR: suitable
杂质
≤0.005% water
water
折射率
n20/D 1.326 (lit.)
bp
65.4 °C (lit.)
mp
-99 °C (lit.)
密度
0.888 g/mL at 25 °C (lit.)
SMILES字符串
[2H]OC([2H])([2H])[2H]
InChI
1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChI key
OKKJLVBELUTLKV-MZCSYVLQSA-N
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一般描述
甲醇-d4（CD3OD）是一种氘代核磁共振溶剂，可用于核磁共振研究和分析。据报道，CD3OD 的绝对红外吸收度在 8000 和 350cm-1 之间。
应用
甲醇-d4 可用作分析樟脑和降樟脑二甲基缩酮中甲氧基交换速率的溶剂。
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警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
靶器官
Eyes,Central nervous system
WGK
WGK 2
法规信息
危险化学品
美国出口管控1C298产品
Infrared intensities of liquids. XVII. Infrared refractive indices from 8000 to 350 cm-1, absolute integrated absorption intensities, transition moments, and dipole moment derivatives of methan-d3-ol and methanol-d4 at 25?C.
Bertie JE and Zhang SL.
J. Chem. Phys. , 101(10), 8364-8379 (1994)
The Rates of Methoxyl Exchange of Camphor and Norcamphor Dimethyl Ketals in Methanol-d4.
Traylor TG and Perrin CL.
Journal of the American Chemical Society, 88(21), 4934-4942 (1966)
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
Jon Kapla et al.
Physical chemistry chemical physics : PCCP, 17(34), 22438-22447 (2015-08-08)
The disaccharide trehalose (TRH) strongly affects the physical properties of lipid bilayers. We investigate interactions between lipid membranes formed by 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and TRH using NMR spectroscopy and molecular dynamics (MD) computer simulations. We compare dipolar couplings derived from DMPC/TRH
William L Scott et al.
Journal of combinatorial chemistry, 11(1), 34-43 (2008-12-25)
For the successful implementation of Distributed Drug Discovery (D(3)) (outlined in the accompanying Perspective), students, in the course of their educational laboratories, must be able to reproducibly make new, high quality, molecules with potential for biological activity. This article reports
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