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Merck
CN

56776

Sigma-Aldrich

三己基(十四烷基)膦二氰胺

≥95% (qNMR)

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别名:
十四烷基三己基膦二氰胺
线性分子式:
[CH3(CH2)5]3P[N(CN)2](CH2)13CH3
分子量:
549.90
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥95% (qNMR)

密度

0.90 g/mL at 20 °C (lit.)

SMILES字符串

N#C[N-]C#N.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C32H68P.C2N3/c1-5-9-13-17-18-19-20-21-22-23-24-28-32-33(29-25-14-10-6-2,30-26-15-11-7-3)31-27-16-12-8-4;3-1-5-2-4/h5-32H2,1-4H3;/q+1;-1

InChI key

DOMOOBQQQGXLGU-UHFFFAOYSA-N

应用

Trihexyltetradecylphosphonium dicyanamide is an ionic liquid that can be used:
  • As an extraction solvent for the separation of organic compounds.
  • In the experiment to study the solubility of carbon dioxide and binary gas mixtures in ionic liquids.
  • To prepare hybrid ionogels having electrochemical applications.
  • As a solvent for the extraction of aromatics from pyrolytic sugars.

注意

储存中可能略微变混浊

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Application of trihexyltetradecylphosphonium dicyanamide ionic liquid for various types of separations problems: Activity coefficients at infinite dilution measurements utilizing GLC method
Kabane B and Redhi GG
Fluid Phase Equilibria, 493, 181-187 (2019)
High pressure solubility of CO2 in non-fluorinated phosphonium-based ionic liquids
Ramdin M, et al.
Journal of Supercritical Fluids, 82, 41-49 (2013)
Solubility of CO2/CH4 gas mixtures in ionic liquids
Ramdin M, et al.
Fluid Phase Equilibria, 375, 134-142 (2014)
Photo-patternable hybrid ionogels for electrochromic applications
Kavanagh A, et al.
Journal of Materials Chemistry, 21(24), 8687-8693 (2011)
Xiaohua Li et al.
Bioresource technology, 216, 12-18 (2016-05-24)
Fermentative bioethanol production from pyrolytic sugars was improved via aromatics removal by liquid-liquid extraction. As solvents, the ionic liquid (IL) trihexyltetradecylphosphonium dicyanamide (P666,14[N(CN)2]) and ethyl acetate (EA) were compared. Two pyrolytic sugar solutions were created from acid-leached and untreated pinewood

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