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Merck
CN

566950

Sigma-Aldrich

4-溴苄硫醇

97%

别名:

4-溴苄基硫醇, 4-溴苯甲基硫醇

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About This Item

线性分子式:
BrC6H4CH2SH
CAS号:
分子量:
203.10
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

97%

mp

27-31 °C (lit.)

SMILES字符串

SCc1ccc(Br)cc1

InChI

1S/C7H7BrS/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2

InChI key

CUCKXDPCCYHFMQ-UHFFFAOYSA-N

应用

4-Bromobenzyl mercaptan may be used to synthesize 4-bromotoluene via desulfurization with molybdenum hexacarbonyl [Mo(CO)6] in tetrahydrofuran.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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?Transition-metal promoted reactions. 12. Molybdenum hexacarbonyl-promoted reductive cleavage of the carbon-sulfur bond?
Luh YT and Wong SC
The Journal of Organic Chemistry, 50(25), 5413-5415 (1985)
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Nature communications, 8(1), 1965-1965 (2017-12-08)
Metalloproteinase inhibitors often feature hydroxamate moieties to facilitate the chelation of metal ions in the catalytic center of target enzymes. Actinonin and matlystatins are  potent metalloproteinase inhibitors that comprise rare N-hydroxy-2-pentyl-succinamic acid warheads. Here we report the identification and characterization of their biosynthetic

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