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方案
97%
表单
solid
mp
76-81 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)c1ccsc1N
InChI
1S/C6H7NO2S/c1-9-6(8)4-2-3-10-5(4)7/h2-3H,7H2,1H3
InChI key
DGGJQLCAYQCPDD-UHFFFAOYSA-N
应用
Methyl 2-aminothiophene-3-carboxylate may be used to prepare 3-thiaisatoic anhydride via hydrolysis, followed by the reaction with phosgene.
Methyl 2-aminothiophene-3-carboxylate may be used to synthesize the following:
- thieno[2,3-d]pyrimidine-2,4(1H,3H)-dione
- thieno[2,3-d]pyrimidin-4(3H)one via reaction with formamide
- methyl 2-(2,5-dimethyl-1H-pyrrol-1-yl)thiophene-3-carboxylate via reaction with hexane-2,5-dione
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
"Design, synthesis and biological evaluation of 4-anilinothieno [2, 3-d] pyrimidine-based hydroxamic acid derivatives as novel histone deacetylase inhibitors"
Zhu W, et al.
Bioorganic & Medicinal Chemistry, 22(21), 6146-6155 (2014)
"The highly potent and selective dipeptidyl peptidase IV inhibitors bearing a thienopyrimidine scaffold effectively treat type 2 diabetes"
Deng J, et al.
European Journal of Medicinal Chemistry, 46(1), 71- 76 (2011)
"Chemistry of Ring-Fused Oxazine-2, 4-diones"
lette Y, et al. et al.
European Journal of Organic Chemistry, 2009(21), 3487-3503 (2009)
"Synthesis of novel 5-chlorinated 2-aminothiophenes using 2, 5-dimethylpyrrole as an amine protecting group"
Puterova Z, et al.
Journal of Heterocyclic Chemistry, 45(1), 201-207 (2008)
?Synthesis, immunosuppressive activity and structure?activity relationship study of a new series of 4-N-piperazinyl-thieno [2, 3-d] pyrimidine analogues"
Jang Y-M, et al.
Bioorganic & Medicinal Chemistry Letters, 20(3), 844-847 (2010)
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