所有图片(1)
About This Item
线性分子式:
Br(CH3)C6H3NH2
CAS号:
分子量:
186.05
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
95%
折射率
n20/D 1.6030 (lit.)
沸点
105-107 °C/205 mmHg (lit.)
密度
1.4780 g/mL at 25 °C (lit.)
官能团
bromo
SMILES字符串
Cc1cccc(Br)c1N
InChI
1S/C7H8BrN/c1-5-3-2-4-6(8)7(5)9/h2-4H,9H2,1H3
InChI key
LDUCMSVRKKDATH-UHFFFAOYSA-N
应用
2-Bromo-6-methylaniline can be used as a reactant to synthesize:
- Alkyl substituted bromoindazole building blocks by Pd-catalyzed Suzuki coupling reaction with various vinyl boronic acids.
- Difluoropyridoindole via Pd-catalyzed intramolecular Heck reaction with difluoropiperidinone.
- 4-Methyl-N-phenyl-1H-benzo[d]imidazol-2-amine by one-pot Cu-catalyzed domino C-N cross-coupling reaction with iodobenzene and thiourea.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
215.1 °F - closed cup
闪点(°C)
101.7 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis and evaluation of indazole based analog sensitive Akt inhibitors
Okuzumi T, et al.
Molecular Biosystems, 6(8), 1389-1402 (2010)
Novel synthesis of 4, 4-difluoropyrido [4, 3-b] indoles via intramolecular Heck reaction
Madaiah M, et al.
Tetrahedron Letters, 54(11), 1424-1427 (2013)
Copper-promoted one-pot approach: Synthesis of benzimidazoles
Boddapati SN, et al.
Molecules (Basel), 25(8), 1788-1788 (2020)
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