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质量水平
方案
97%
表单
solid
mp
48-52 °C (lit.)
官能团
bromo
chloro
SMILES字符串
Clc1ccc(CBr)cc1
InChI
1S/C7H6BrCl/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2
InChI key
KQNBRMUBPRGXSL-UHFFFAOYSA-N
一般描述
4-Chlorobenzyl bromide undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid. It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.
应用
4-Chlorobenzyl bromide may be used to synthesize 1-(4-chlorobenzyl)-2-(pyrrolidin-1-yl-methyl)-1H-benzimidazole dihydrochloride
包装
4-Chlorobenzyl bromide may be used to synthesize:
- 1-[1-[2-[(4-chlorobenzyl)thio]phenyl]vinyl]-1H-imidazole
- 6-[4-(4-chlorobenzyl)piperazinyl]chromane
- N,N′-bis(4-chlorobenzyl)piperazine
- N-(4-chlorobenzyl)piperazine
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
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Synthesis and antifungal activity of new 1-vinylimidazoles.
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Gas-phase chemistry of benzyl cations in dissociation of N-benzylammonium and N-benzyliminium ions studied by mass spectrometry.
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Journal of the American Society For Mass Spectrometry, 23(5), 823-833 (2012)
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