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反应适用性
reagent type: reductant
质量水平
浓度
3 M in methylene chloride
密度
1.321 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
Cl[BH-](Cl)[O+]1CCOCC1
InChI
1S/C4H9BCl2O2/c6-5(7)9-3-1-8-2-4-9/h5H,1-4H2
InChI key
RCKKTUSYECYDLY-UHFFFAOYSA-N
应用
Reactant for:
- Hydroboration reactions
- Preparation of alkenyl- and alkylboronic acids
可易于代替常用硼氢化试剂，例如 BH3、THF 和 BMS。
法律信息
U.S. Pat. No. 6,008,414
警示用语：
Danger
危险声明
危险分类
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Central nervous system
补充剂危害
WGK
WGK 3
闪点(°F)
221.0 °F
闪点(°C)
105 °C
Kanth, J. V. B.; Brown, H. C.
Organic Letters, 1, 315-315 (1999)
J V Kanth et al.
The Journal of organic chemistry, 66(16), 5359-5365 (2001-08-04)
Several less volatile oxygen-containing Lewis bases, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and monoglyme, were examined as prospective mono- and dichloroborane carriers. Dioxane, ethyl acetate, and beta-chloroethyl ether form relatively stable boron trichloride adducts, but
Josyula, K. V. B. et al
Tetrahedron Letters, 44, 7789-7789 (2003)
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