所有图片(1)
About This Item
线性分子式:
(CH3)2CHNC
CAS号:
分子量:
69.11
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
折射率
n20/D 1.371 (lit.)
沸点
75 °C (lit.)
密度
0.733 g/mL at 25 °C (lit.)
官能团
amine
isonitrile
储存温度
2-8°C
SMILES字符串
CC(C)[N+]#[C-]
InChI
1S/C4H7N/c1-4(2)5-3/h4H,1-2H3
InChI key
MJZUMMKYWBNKIP-UHFFFAOYSA-N
一般描述
Isopropyl isocyanide is an alkyl isocyanide.
应用
Isopropyl isocyanide may be used in the preparation of:
- Ugi ligand A2C11I1, which is employed in the solid-phase Ugi synthesis.
- Pentafluorophenyl (PFP) functional monomers, via Passerini reaction.
- Dinuclear copper complex [Cu2(μ-PiPr2bipy)2{μ-CNCH(CH3)2}](PF6)2 [PiPr2bipy = 6-(diisopropylphosphanyl)-2,2′-bipyridine].
- (3E)-(Imino)thiaisoindoline 1,1-dioxide derivative.
- N,N′-diisopropylcarbodiimide (DIC) analog via reaction with propan-2-amine.
- 1-t-butyl-2-isopropyldiaziridinone via reaction with 2-methyl-2-nitrosopropane
- isopropyl isocyanate via reaction with ozone
- 1-phthalimidoazetidines via [1+3]cycloaddition reaction with 1-pththalimidoaziridines
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
69.1 °F - closed cup
闪点(°C)
20.6 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
[1+ 3] Cycloadditions of isocyanides to azomethine ylides; synthesis and properties of 1-phthalimidoazetidines
Charrier J, et al.
The Journal of Organic Chemistry, 48(4), 481-486 (1983)
Reaction of Alkyl Isocyanides with Ozone. A New Isocyanate Synthesis1
Feuer H, et al.
The Journal of Organic Chemistry, 23(8), 1107-1109 (1958)
A synthetic Protein G adsorbent based on the multi-component Ugi reaction for the purification of mammalian immunoglobulins.
Qian J, et al.
Journal of Chromatography. B, Biomedical Applications, 898, 15-23 (2012)
Palladium-Catalyzed C C Coupling of Aryl Halides with Isocyanides: An Alternative Method for the Stereoselective Synthesis of (3E)-(Imino) isoindolin-1-ones and (3E)-(Imino) thiaisoindoline 1, 1-Dioxides.
Liu B, et al.
Advanced Synthesis & Catalysis, 354(11-12), 2288-2300 (2012)
A Series of Dinuclear Copper Complexes Bridged by Phosphanylbipyridine Ligands: Synthesis, Structural Characterization and Electrochemistry.
Lilio AM, et al.
European Journal of Organic Chemistry, 22-23, 4016-4023 (2013)
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