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Merck
CN

553077

Sigma-Aldrich

4-戊烯腈

97%

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线性分子式:
CH2=CHCH2CH2CN
CAS号:
分子量:
81.12
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

97%

折射率

n20/D 1.42 (lit.)

bp

140 °C (lit.)

密度

0.814 g/mL at 25 °C (lit.)

SMILES字符串

C=CCCC#N

InChI

1S/C5H7N/c1-2-3-4-5-6/h2H,1,3-4H2

InChI key

CFEYBLWMNFZOPB-UHFFFAOYSA-N

一般描述

4-Pentenenitrile (4-PN) is a terminal alkene nitrile. It is obtained from 3-pentenenitrile via cationic nickel hydride or cobalt catalyzed isomerization. 4-Pentenenitrile undergoes hydrocyanation in the presence of bidentate nickel complexes (catalysts) to yield 3-pentenenitrile. 4-PN undergoes gas-phase reaction with OH radicals and Cl atoms in the presence of synthetic air and various reference compounds.

应用

4-Pentenenitrile may be used to synthesize 4-pentenylamine.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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B Ozierenski et al.
Die Nahrung, 37(1), 5-14 (1993-01-01)
The effects of 5-vinyloxazolidine-2-thione (VOT), 1-cyano-3-butene (CYB) and various isothiocyanates on parameters of hepatic phase I and phase II biotransformation were investigated in male rats after oral treatment for 3 consecutive days. The compounds with the exception of CYB caused
New methods for alkaloid synthesis: Generation of indole-2, 3-diquinomethanes as a route to indole alkaloids.
Gallagher T and Magnus P.
Tetrahedron, 37(23), 3889-3897 (1981)
Gas-phase reactivity study of (E)-3-pentenenitrile and 4-pentenenitrile towards OH radicals and Cl atoms at atmospheric pressure.
Colomer JP, et al.
Atmospheric Environment, 61, 597-604 (2012)
Kinetic control in catalytic olefin isomerization. An explanation for the apparent contrathermodynamic isomerization of 3-pentenenitrile.
McKinney RJ.
Organometallics, 4(6), 1142-1143 (1985)
P Kloss et al.
Poultry science, 73(10), 1542-1551 (1994-10-01)
Glucosinolates and their breakdown products (nitriles) have long been implicated as toxic factors when feeding rapeseed (Brassica napus) meals and crambe (Crambe abyssinica) meals to poultry. Accordingly, various methods have been developed to remove these compounds from the meals to

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