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质量水平
方案
98%
mp
59-63 °C (lit.)
SMILES字符串
[O-][n+]1ccccc1-c2ccccn2
InChI
1S/C10H8N2O/c13-12-8-4-2-6-10(12)9-5-1-3-7-11-9/h1-8H
InChI key
KIKATWFLYDKKOL-UHFFFAOYSA-N
一般描述
2,2′-Dipyridyl N-oxide is a mono-N-oxide of 2,2′-bipyridine. It is widely used as a chelating agent. 2,2′-Bipyridine N-oxide readily forms complexes with transition metal perchlorates and divalent 3d metal nitrates. It can be prepared from 2,2′-bipyridyl.
应用
2,2′-Dipyridyl N-oxide(Obpy) may be used to synthesize the following:
- 2,2′-bipyridyl-6-carbonitrile
- 4-nitro-2,2′-bipyridyl N-oxide by reaction with potassium nitrate in sulfuric acid
- Eu(TTA)3(Obpy), an electroluminescent red emitter obtained via reaction with europium(III) chloride hexahydrate (EuCl3.6H2O) and 2-thenoyltrifluoroacetonate(TTA)
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
N*-N*-S* tridentate ligand system as potential antitumor agents.
Journal of Medicinal Chemistry, 24(10), 1181-1184 (1981)
2, 2'-Bipyridine N-oxide chelates with divalent 3d metal perchlorates.
Inorganic Chemistry, 12(6), 1221-1226 (1973)
An efficient electroluminescent (2, 2'-bipyridine mono N-oxide) europium (III) ?-diketonate complex
Journal of Materials Chemistry, 14(18), 2732-2734 (2004)
Bipyridyl substituted triazoles as hole-blocking and electron-transporting materials for organic light-emitting devices.
Organic Electronics, 9(1), 77-84 (2008)
2, 2'-bipyridine n-oxide and 1, 10-phenanthroline n-oxide complexes with divalent 3d metal nitrates.
J. Inorg. Nucl. Chem., 36(12), 3751-3761 (1974)
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