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Merck
CN

551899

Sigma-Aldrich

2,3-二氨基-5-溴吡啶

97%

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经验公式(希尔记法):
C5H6BrN3
CAS号:
分子量:
188.03
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

mp

155 °C (dec.) (lit.)

SMILES字符串

Nc1cc(Br)cnc1N

InChI

1S/C5H6BrN3/c6-3-1-4(7)5(8)9-2-3/h1-2H,7H2,(H2,8,9)

InChI key

YRGMYJUKFJPNPD-UHFFFAOYSA-N

一般描述

2,3-Diamino-5-bromopyridine can be prepared from 2-amino-3-nitro-5-bromopyridine via reduction using stannous chloride.

应用

2,3-Diamino-5-bromopyridine may be used in the preparation of the following heterocyclic compounds:
  • 6-bromoimidazo-[b]pyridine
  • 11-bromopyrido[2′,3′:5,6]pyrazino[2,3-f][1,10]phenanthroline
  • 6-bromo-3-(tetrahydro-2H-pyran-2-yl)-3H-imidazo[4,5-b]pyridine

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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Microwave-Assisted C-2 Direct Alkenylation of Imidazo [4, 5-b] pyridines: Access to Fluorescent Purine Isosteres with Remarkably Large Stokes Shifts.
Baladi T, et al.
European Journal of Organic Chemistry, 2016(14), 2421-2434 (2016)
Metabolite analogs. VIII. Syntheses of some imidazopyridines and pyridotriazoles.
Graboyes H and Day AR.
Journal of the American Chemical Society, 79(24), 6421-6426 (1957)
Re (I) Complexes of Substituted dppz: A Computational and Spectroscopic Study.
van der Salm H, et al.
Inorganic Chemistry, 53(6), 3126-3140 (2014)
Magda A Akl et al.
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Worldwide, prostate cancer is considered to be one of the three most commonly occurring cancers amongst the male population. Clinically, early detection of diverse forms of cancer before they spread and become incurable plays an important role in treatment strategy.
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Bilirubin, a key biomarker for the jaundice and its clinical diagnosis needs a better analytical tool. A novel and simple fluorescent platform based on (2,2'-((1E,1'E)-((6-bromopyridine-2,3-diyl) bis(azanylylidene)) bis(methanylylidene diphenol) (BAMD) was designed. BAMD showed a remarkable fluorescent intensity with a very

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