55083
8-羟基喹啉-2-甲醛
≥98.0% (GC)
别名:
2-甲酰-8-喹啉醇, 2-甲酰-8-羟基喹啉, 8-羟基喹啉-2-甲醛
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选择尺寸
关于此项目
经验公式（希尔记法）:
C10H7NO2
化学文摘社编号:
分子量:
173.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
127519
产品名称
8-羟基喹啉-2-甲醛, ≥98.0% (GC)
InChI
1S/C10H7NO2/c12-6-8-5-4-7-2-1-3-9(13)10(7)11-8/h1-6,13H
SMILES string
Oc1cccc2ccc(C=O)nc12
InChI key
SLBPIHCMXPQAIQ-UHFFFAOYSA-N
assay
≥98.0% (GC)
form
solid
mp
97-100 °C
functional group
aldehyde
Quality Level
Application
8-羟基-2-喹啉甲醛（8-羟基喹啉-2-甲醛）可用于以下制备过程：
- 8-羟基-2-喹啉-1-氨基芘与 1-氨基芘的席夫碱反应
- ( E )-2-（（2-（吡啶-2-基）肼基）甲基）喹啉-8-醇（与 2-肼基吡啶偶联）
- 8-羟基喹啉-2-甲醛肟
- 2-[（8-羟基喹啉）-2-甲基氨基乙基]-β- D -吡喃葡萄糖苷
General description
以 2-甲基喹啉-8-醇为原料，二氧化硒为氧化剂，经氧化制得 8-羟基-2-喹啉甲醛。
Other Notes
合成络合剂的结构单元
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Ayaan Saleem et al.
Dalton transactions (Cambridge, England : 2003), 47(17), 6156-6165 (2018-04-19)
One-pot reaction between 8-hydroxyquinoline-2-carboxaldehyde (HQC) and tris(hydroxymethyl)aminomethane (TRIS) followed by in situ cyclization yielded an oxazolidine based ligand which produced four mononuclear complexes of MnII(1), CoII(2), NiII(3), ZnII(4), a tetranuclear iron (FeIII4) complex (5) and a trinuclear cobalt (CoIICoIII2) complex
S-shaped decanuclear heterometallic [Ni8Ln2] complexes [Ln (iii)= Gd, Tb, Dy and Ho]: theoretical modeling of the magnetic properties of the gadolinium analogue.
Hossain S, et al.
Dalton Transactions, 43(26), 10164-10174 (2014)
Rhombus-shaped tetranuclear [Ln4] complexes [Ln= Dy (III) and Ho (III)]: synthesis, structure, and SMM behavior.
Chandrasekhar V, et al.
Inorganic Chemistry, 52(11), 6346-6353 (2013)
Nadia Alessandra Carmo Dos Santos et al.
Dalton transactions (Cambridge, England : 2003), 46(47), 16455-16464 (2017-11-17)
Novel cobalt, nickel, and iron complexes based on the pentadentate 8-hydroxyquinoline-di(2-picolyl)amine ligand were synthesized and thoroughly characterized. X-ray structures of both the cobalt and iron complexes were also obtained, showing the tendency to adopt a pseudo-octahedral geometry by coordination of
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