550574
甲醇-OD
99 atom % D
别名:
mono-Deuteromethanol, Methyl alcohol-OD, 氘代甲醇-d
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关于此项目
线性分子式:
CH3OD
化学文摘社编号:
分子量:
33.05
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
215-933-0
Beilstein/REAXYS Number:
1730948
MDL number:
Assay:
≥99.00%
Technique(s):
NMR: suitable
Bp:
65.5 °C (lit.)
InChI key
OKKJLVBELUTLKV-VMNATFBRSA-N
InChI
1S/CH4O/c1-2/h2H,1H3/i2D
SMILES string
[2H]OC
isotopic purity
99 atom % D
assay
≥99.00%
form
liquid
expl. lim.
5.5-36.5 % (lit.)
technique(s)
NMR: suitable
impurities
≤0.0250% water
water
refractive index
n20/D 1.327 (lit.)
bp
65.5 °C (lit.)
mp
-99 °C (lit.)
density
0.813 g/mL at 25 °C (lit.)
mass shift
M+1
Quality Level
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General description
氘代甲醇是甲醇的氘代形式。在基于NMR的科研和分析中用作溶剂。
Application
甲醇-OD 可被用作氘代试剂用于：
- APPI HDX MS (大气压光电离氢/氘交换质谱）检测。
- 由1,4-丁二醇-D8 合成 1,4-丁二醇-D6(1,4-BD-D6)。
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
target_organs
Eyes,Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
51.8 °F - closed cup
flash_point_c
11.0 °C - closed cup
法规信息
危险化学品
美国出口管控产品
此项目有
Dehydration of alcohols over alumina. VIII. Ether formation from the deuterated methanols CH3OH, CD3OH, CH3OD, and CD3OD.
Knozinger H, et al.
The Journal of Physical Chemistry, 72(8), 2770-2774 (1968)
The Raman Spectra of the Methyl Alcohols, CH3OH, CH3OD, and CH2DOD.
Halford JO, et al.
J. Chem. Phys. , 5(12), 927-932 (1937)
High Resolution Fourier Transform Far Infrared Spectroscopy of CH3OD.
Mukhopadhyay I, et al.
Journal of Molecular Spectroscopy, 186(1), 15-21 (1997)
Infrared intensities of liquids XXI: integrated absorption intensities of CH3OH, CH3OD, CD3OH and CD3OD and dipole moment derivatives of methanol.
Bertie JE and Zhang SL.
Journal of Molecular Structure, 413, 333-363 (1997)
A New Analysis of the Rotational Spectrum of CH3OD.
Anderson T, et al.
Journal of Molecular Spectroscopy, 159(2), 410-421 (1993)
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