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Merck
CN

550256

甲烷磺酸银

solid

别名:

甲基磺酸银, 甲烷磺酸 银盐

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关于此项目

线性分子式:
AgSO3CH3
化学文摘社编号:
分子量:
202.97
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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产品名称

甲烷磺酸银,

表单

solid

质量水平

反应适用性

core: silver
reagent type: catalyst

mp

252-256 °C (lit.)

SMILES字符串

[Ag+].CS([O-])(=O)=O

InChI

1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

InChI key

MLKQJVFHEUORBO-UHFFFAOYSA-M

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应用

用于催化:
  • 杂环化反应
  • CO 2 介导炔丙醇重排合成 α,ß-不饱和酮和酯

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Chad E Wujcik et al.
Journal of separation science, 33(6-7), 826-833 (2010-01-21)
Hydrophilic retention coefficients for 17 peptides were calculated based on retention coefficients previously published for TSKgel silica-60 and were compared with the experimental elution profile on a Waters Atlantis HILIC silica column using TFA and methanesulfonic acid (MSA) as ion-pairing
Siddheshwar K Chauthe et al.
Bioorganic & medicinal chemistry letters, 22(6), 2251-2256 (2012-02-22)
A series of dimeric phloroglucinol compounds were synthesized in a single step using commercially available phloroglucinol and methanesulfonic acid. Based on the reported anticancer activity of plant derived dimeric phloroglucinols, these synthesized compounds were evaluated for their in vitro anti-proliferative
Claudio Pettinari et al.
Inorganic chemistry, 50(21), 11173-11183 (2011-10-18)
Five new silver(I) complexes of formulas [Ag(Tpms)] (1), [Ag(Tpms)(PPh(3))] (2), [Ag(Tpms)(PCy(3))] (3), [Ag(PTA)][BF(4)] (4), and [Ag(Tpms)(PTA)] (5) {Tpms = tris(pyrazol-1-yl)methanesulfonate, PPh(3) = triphenylphosphane, PCy(3) = tricyclohexylphosphane, PTA = 1,3,5-triaza-7-phosphaadamantane} have been synthesized and fully characterized by elemental analyses, (1)H, (13)C
Eric D Nacsa et al.
Organic letters, 15(1), 38-41 (2012-12-15)
The cyclopropenone catalyzed nucleophilic substitution of alcohols by methanesulfonate ion with inversion of configuration is described. This work provides an alternative to the Mitsunobu reaction that avoids the use of azodicarboxylates and generation of hydrazine and phosphine oxide byproducts. This
Cassandra J Gaston et al.
Environmental science & technology, 44(5), 1566-1572 (2010-02-04)
Dimethyl sulfide (DMS), produced by oceanic phytoplankton, is oxidized to form methanesulfonic acid (MSA) and sulfate, which influence particle chemistry and hygroscopicity. Unlike sulfate, MSA has no known anthropogenic source making it a useful tracer for ocean-derived biogenic sulfur. Despite

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