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方案
96%
折射率
n20/D 1.566 (lit.)
沸点
197 °C (lit.)
密度
1.36 g/mL at 25 °C (lit.)
SMILES字符串
COc1ccc(Br)c(C)c1C
InChI
1S/C9H11BrO/c1-6-7(2)9(11-3)5-4-8(6)10/h4-5H,1-3H3
InChI key
WOWNZZYJCUUIFC-UHFFFAOYSA-N
一般描述
4-Bromo-2,3-dimethylanisole can be prepared from 2,3-dimethylanisole via bromination using N-bromosuccinimide-acetonitrile (NBS-CH3CN) system.
应用
4-Bromo-2,3-dimethylanisole may be used in the preparation of:
- 4,6-Dibromo-2,3-dimethylanisole via bromination using NBS-CH3CN system.
- 4-Methoxy-2,2′,3,3′-tetramethyldiphenyl ether by reacting with 2,3-dimethylphenol.
- A novel arylsulfonamide derivative with potent glucocorticoid receptor (GR) agonist activity.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Oxidative coupling of phenols. Part 9. The role of steric effects in the oxidation of methyl-substituted phenols.
Armstrong DR, et al.
J. Chem. Soc. Perkin Trans. II, 5, 581-585 (1983)
N-Bromosuccinimide in acetonitrile: A mild and regiospecific nuclear brominating reagent for methoxybenzenes and naphthalenes.
Carreno MC, et al.
The Journal of Organic Chemistry, 60(16), 5328-5331 (1995)
Substituted phenyl as a steroid A-ring mimetic: Providing agonist activity to a class of arylsulfonamide nonsteroidal glucocorticoid ligands.
Darren D, et al.
Bioorganic & Medicinal Chemistry Letters, 23(24), 6645-6649 (2013)
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