所有图片(1)
别名:
4-tert-Butylbenzenemethanethiol, 4-tert-Butylbenzylthiol, 4-tert-Butylphenylmethanethiol, p-tert-Butylbenzenemethanethiol, p-tert-Butylbenzyl mercaptan
线性分子式:
(CH3)3CC6H4CH2SH
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折射率
n20/D 1.5430 (lit.)
质量水平
bp
102-103 °C/3.1 mmHg (lit.)
密度
0.966 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)(C)c1ccc(CS)cc1
InChI
1S/C11H16S/c1-11(2,3)10-6-4-9(8-12)5-7-10/h4-7,12H,8H2,1-3H3
InChI key
UIYKSYBJKIMANV-UHFFFAOYSA-N
一般描述
4-tert-Butylbenzyl mercaptan is a benzyl mercaptan derivative that is commonly used as a ligand for synthesizing metal clusters.
应用
4-tert-Butylbenzyl mercaptan (BBSH) may be used in the preparation of N-Me-aminopyrimidinone derivatives, which are potent state-dependent inhibitor of Nav1.7 (Nav= voltage-gated sodium channel). It may also be used to synthesize organic-soluble, atomically precise array of silver clusters via a novel approach based on the miscibility principle while avoiding the use of phase-transfer agents.
Reactant for:
- Stereoselective thiourea-catalyzed sulfa-Michael addition
- Nucleophilic substitution reactions
- Urea-catalyzed trans-thioesterification
- Sc-catalyzed Michael addition
- Copper-catalyzed decarboxylative cross-coupling
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hanh Nho Nguyen et al.
Bioorganic & medicinal chemistry letters, 22(2), 1055-1060 (2012-01-03)
Clinical genetic data have shown that the product of the SCN9A gene, voltage-gated sodium ion channel Nav1.7, is a key control point for pain perception and a possible target for a next generation of analgesics. Sodium channels, however, historically have
Luminescent AgAu Alloy Clusters Derived from Ag Nanoparticles-Manifestations of Tunable AuI-CuI Metallophilic Interactions.
Krishnadas KR, et al.
European Journal of Inorganic Chemistry, 2014(5), 908-916 (2014)
Synthesis of atomically precise silver clusters by using the miscibility principle.
Ghosh A and Pradeep T.
European Journal of Organic Chemistry, 2014(31), 5271-5275 (2014)
Formation of an NIR-emitting Ag34S3SBB20(CF3COO)62+ cluster from a hydride-protected silver cluster.
C K Manju et al.
Dalton transactions (Cambridge, England : 2003), 48(24), 8664-8670 (2019-05-29)
Recent reports have shown that the intercluster reaction is a new synthetic strategy to prepare alloy clusters. In this work, we performed an intercluster reaction between silver clusters and produced highly ionizable Ag-S-type clusters; we examined their formation by mass
Nan Yan et al.
Science advances, 4(10), eaat7259-eaat7259 (2018-10-20)
The transition from nanocluster to nanocrystal is a central issue in nanoscience. The atomic structure determination of metal nanoparticles in the transition size range is challenging and particularly important in understanding the quantum size effect at the atomic level. On
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