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Merck
CN
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安全信息

547816

Sigma-Aldrich

三[N,N-双(三甲基硅烷)胺]铕(III)

98%

别名:

1,1,1-Trimethyl-N-(trimethylsilyl)silanamine europium salt

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About This Item

线性分子式:
Eu(N(Si(CH3)3)2)3
CAS号:
35789-02-7
分子量:
633.12
MDL编号:
MFCD03411248
UNSPSC代码:
12352300
PubChem化学物质编号:
24878982
NACRES:
NA.22

方案

98%

表单

solid

反应适用性

core: europium
reagent type: catalyst

mp

147-154 °C (lit.)

SMILES字符串

C[Si](C)(C)N([Eu](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/3C6H18NSi2.Eu/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

InChI key

FLADHQMJJLOUHM-UHFFFAOYSA-N

应用

Reactant for:
  • Preferential complexation reactions
  • Pin-wheel shaped heterobimetallis lanthanide alkali metal binaphtholates

Reactant for synthesis of:
  • Isostructural neo-pentoxide derivatives of Group 3 and lanthanide series metals for production of Ln2O3 nanoparticles
  • Anhydrous mononuclear tris(8-quinolinolato)lanthanoid complexes for organic light-emitting devices

象形图

FlameCorrosion
GHS02,GHS05

警示用语：

Danger

危险声明

H228,H261,H314

危险分类

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

补充剂危害

EUH014

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

闪点(°F)

36.0 °F - closed cup

闪点(°C)

2.2 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCG8848
MKBL2760V
MKBK2928V
MKBJ8752V
16414CO

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Jerry Isaacson et al.
Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)
(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an
A Sebok et al.
Journal of chromatography. A, 1211(1-2), 104-112 (2008-10-14)
This paper presents a derivatization, mass fragmentation study relating to the most common six cholic acids, such as cholic, lithocholic, chenodeoxycholic, ursodeoxycholic, 3-hydroxy,7-ketocholanic and dehydrocholic acids, identified and quantified as pollutants in the aquatic environment at the first time. Derivatizations
Marko Marinkovic et al.
Advanced materials (Deerfield Beach, Fla.), 24(29), 4005-4009 (2012-06-26)
A model is presented that describes the gate-voltage-dependent contact resistance and channel-length-dependent charge carrier mobility of small-molecule-based organic thin-film transistors in top and bottom drain/source contact configuration.
Natalie M Clark et al.
Chemical communications (Cambridge, England), (39)(39), 5835-5837 (2009-09-30)
'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.
Werner Mormann et al.
Macromolecular bioscience, 9(4), 369-375 (2008-11-26)
Trimethylsilylation of cellulose in different 1,3-dialkylimidazolium ionic liquids (IL) with hexamethyldisilazane (HMDS) as a silylating agent was investigated. Trimethylsilyl (TMSi) cellulose with a degree of substitution (DS) greater than 1 is insoluble in the IL. The maximum DS obtained depends
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