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质量水平
方案
97%
表单
powder or crystals
mp
48-52 °C (lit.)
官能团
ketone
sulfone
SMILES字符串
CC(=O)CS(C)(=O)=O
InChI
1S/C4H8O3S/c1-4(5)3-8(2,6)7/h3H2,1-2H3
InChI key
NWEYGXQKFVGUFR-UHFFFAOYSA-N
一般描述
Methanesulfonylacetone is a sulfonyl group-containing active methylene compound. It can react with Baylis–Hillman acetates in dimethylformamide/potassium carbonate system to form ortho-hydroxyacetophenone derivatives.
应用
Methanesulfonylacetone may be used in the preparation of 6-bromo-3-methanesulfonyl-2-methyl-quinolin-4-ol.
Reactant for:
- Stereoselective preparation of chiral cyclic ketones
- Preparation of poly-substituted pyridines
- Multicomponent cyclocondensation with aldehydes and aminoazoles
- Gold-catalyzed Friedlander cyclocondensation reaction
- Radical homoallylation reactions
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
New vistas in quinoline synthesis.
Atechian S, et al.
Tetrahedron, 63(13), 2811-2823 (2007)
Synthesis of ortho-hydroxyacetophenone derivatives from Baylis?Hillman acetates.
Kim JN, et al.
Tetrahedron Letters, 43(37), 6597-6600 (2007)
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