推荐产品
质量水平
方案
96%
折射率
n20/D 1.438 (lit.)
沸点
135-136 °C (lit.)
密度
0.896 g/mL at 25 °C (lit.)
官能团
alkyl halide
allyl
chloro
SMILES字符串
ClCCCCC=C
InChI
1S/C6H11Cl/c1-2-3-4-5-6-7/h2H,1,3-6H2
InChI key
BLMIXWDJHNJWDT-UHFFFAOYSA-N
一般描述
6-Chloro-1-hexene is an ω-chloro-1-alkene. It reacts with β-substituted imines in the presence of a rhodium catalyst to afford tri- and tetra-substituted imines. It undergoes cross-coupling reaction in the presence of copper(II) chloride and 1-phenylpropyne.
应用
6-Chloro-1-hexene may be used in the synthesis of 1-(5-hexen)-2,3-dimethyl-imidazolium chloride.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
84.0 °F - closed cup
闪点(°C)
28.9 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Journal of the American Chemical Society, 128.17, 5604-5605 (2006)
The Signs of Si29-H1 and Si29-F19 Coupling Constants
Danyluk SS.
Journal of the American Chemical Society, 86.20, 4504-4505 (1964)
Copper nanoparticle-catalyzed cross-coupling of alkyl halides with Grignard reagents.
Kim JH and Chung YK.
Chemical Communications (Cambridge, England), 49(94), 11101-11103 (2013)
New ionic liquid-modified silica gels as recyclable materials for l-proline-or H?Pro?Pro?Asp?NH2-catalyzed aldol reaction
Aprile C, et al.
Green Chemistry, 9.12, 1328-1334 (2007)
Christopher L Rock et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 461-467 (2018-11-30)
The phosphine-substituted α-diimine Ni precursor, (Ph2PPrDI)Ni, has been found to catalyze alkene hydrosilylation in the presence of Ph2SiH2 with turnover frequencies of up to 124 h-1 at 25 °C (990 h-1 at 60 °C). Moreover, the selective hydrosilylation of allylic
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