所有图片(1)
About This Item
线性分子式:
H2NC6H3(Cl)SH
CAS号:
分子量:
159.64
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
96%
mp
56-61 °C (lit.)
官能团
chloro
SMILES字符串
Nc1cc(Cl)ccc1S
InChI
1S/C6H6ClNS/c7-4-1-2-6(9)5(8)3-4/h1-3,9H,8H2
InChI key
NGIRMPARLVGMPX-UHFFFAOYSA-N
一般描述
2-Amino-4-chlorobenzenethiol reacts with aromatic aldehydes and cyclohexanecarboxaldehyde to afford the corresponding thiazole and thiazoline derivatives. It undergoes oxidation in the presence of 1-n-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)] to form the corresponding symmetrical disulfide.
应用
2-Amino-4-chlorobenzenethiol may be used in the synthesis of:
- 2,3-dihydro-1,5-benzothiazepin-4-(5H)-ones
- 8-chloro-1-azaphenothiazine
- 5-chloro-2-(4-methoxyphenyl)-2,3-dihydro-1,3,2-benzothiazaphosphole 2-sulfide
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
SUBSTITUTED 2,3-DIHYDRO-1,5-BENZOTHIAZEPIN-4(5H)-ONES AND 3,4-DIHYDRO-2-PHENYL-(2H)-1,6-BENZOTHIAZOCIN-5(6H)-ONES.
J KRAPCHO et al.
Journal of medicinal chemistry, 6, 544-546 (1963-09-01)
10-(Dialkylaminoalkyl)-pyrido [3, 2-b][1, 4] benzothiazine (1-azaphenothiazine) and related compounds.
Yale HL and Sowinski F.
Journal of the American Chemical Society, 80(7), 1651-1654 (1958)
"On water? organic synthesis: a highly efficient and clean synthesis of 2-aryl/heteroaryl/styryl benzothiazoles and 2-alkyl/aryl alkyl benzothiazolines.
Chakraborti AK, et al.
Green Chemistry, 9(12), 1335-1340 (2007)
Brajendra S Kusmariya et al.
Journal of molecular modeling, 21(11), 278-278 (2015-10-07)
Three mononuclear coordination complexes of Co(II), Ni(II), and Cu(II) have been synthesized from 2,4-dichloro-6-{(E)-[(5-chloro-2-sulfanylphenyl)imino]methyl}phenol ligand (H 2 L) obtained by simple condensation reaction of 3,5-dichloro-2-hydroxybenzaldehyde and 2-amino-4-chlorobenzenethiol and characterized by elemental analysis, spectral (FT-IR, electronic, and (1)H-NMR), molar conductance, thermal
Base-free oxidation of thiols to disulfides using selenium ionic liquid.
Thurow S, et al.
Tetrahedron Letters, 52(5), 640-643 (2011)
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