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质量水平
检测方案
≥95.0% (sum of enantiomers, HPLC)
≥97.0% (NT)
旋光性
[α]20/D +197±4°, c = 0.25% in ethanol
mp
269-272 °C (lit.)
SMILES字符串
CC[C@H]1CN2CC[C@H]1C[C@@H]2[C@@H](O)c3ccnc4ccccc34
InChI
1S/C19H24N2O/c1-2-13-12-21-10-8-14(13)11-18(21)19(22)16-7-9-20-17-6-4-3-5-15(16)17/h3-7,9,13-14,18-19,22H,2,8,10-12H2,1H3/t13-,14-,18+,19-/m0/s1
InChI key
WFJNHVWTKZUUTR-QAMTZSDWSA-N
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应用
Hydrocinchonine is an alkaloid that can be used as a chiral base in:
- The 1,3-dipolar cycloaddition reactions of alkenes and azomethine ylides using silver fluoride.
- The aza-Henry reaction for the synthesis of molecules with optically active quaternary centers.
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
A convenient procedure for the catalytic asymmetric 1, 3-dipolar cycloaddition of azomethine ylides and alkenes
Organic Letters, 7(21), 4569-4572 (2005)
A chiral molecular recognition approach to the formation of optically active quaternary centres in aza-Henry reactions
Organic & Biomolecular Chemistry, 3(8), 1362-1364 (2005)
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