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方案
97%
旋光性
[α]20/D −53°, c = 1 in THF
mp
145.5-148.5 °C (lit.)
官能团
bromo
InChI
1S/C20H20Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h9-10,23-24H,1-8H2
InChI key
WDRTXCNGVVLRSZ-UHFFFAOYSA-N
一般描述
(S)-3,3′-Dibromo-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2,2′-naphthalenediol can be used in the synthesis of chiral bidentate hybrid ligands for asymmetric hydrogenation and hydroformylation reactions.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Supramolecular hybrid bidentate ligands in asymmetric hydrogenation
Bellini R and Reek JNH
European Journal of Inorganic Chemistry, 2012(29), 4684-4693 (2012)
Coordination studies on supramolecular chiral ligands and application in asymmetric hydroformylation
Bellini R and Reek JNH
Chemistry?A European Journal , 18(23), 7091-7099 (2012)
Supramolecular control of ligand coordination and implications in hydroformylation reactions
Bellini R, et al.
Angewandte Chemie (International ed. in English), 123(32), 7480-7483 (2011)
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