540595
(S)-(-)-3,3′-二溴-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-二-2,2′-萘酚
97%
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关于此项目
经验公式（希尔记法）:
C20H20Br2O2
化学文摘社编号:
分子量:
452.18
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
InChI
1S/C20H20Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h9-10,23-24H,1-8H2
InChI key
WDRTXCNGVVLRSZ-UHFFFAOYSA-N
assay
97%
optical activity
[α]20/D −53°, c = 1 in THF
mp
145.5-148.5 °C (lit.)
functional group
bromo
General description
(S)-3,3′-Dibromo-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2,2′-naphthalenediol can be used in the synthesis of chiral bidentate hybrid ligands for asymmetric hydrogenation and hydroformylation reactions.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Supramolecular control of ligand coordination and implications in hydroformylation reactions
Bellini R, et al.
Angewandte Chemie (International ed. in English), 123(32), 7480-7483 (2011)
Coordination studies on supramolecular chiral ligands and application in asymmetric hydroformylation
Bellini R and Reek JNH
Chemistry?A European Journal , 18(23), 7091-7099 (2012)
Supramolecular hybrid bidentate ligands in asymmetric hydrogenation
Bellini R and Reek JNH
European Journal of Inorganic Chemistry, 2012(29), 4684-4693 (2012)
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