539899
双(五氟苯基)碳酸酯
97%, for peptide synthesis
别名:
五氟苯基碳酸酯
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关于此项目
线性分子式:
(C6F5O)2CO
化学文摘社编号:
分子量:
394.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Beilstein/REAXYS Number:
2029727
产品名称
双(五氟苯基)碳酸酯, 97%
InChI
1S/C13F10O3/c14-1-3(16)7(20)11(8(21)4(1)17)25-13(24)26-12-9(22)5(18)2(15)6(19)10(12)23
SMILES string
Fc1c(F)c(F)c(OC(=O)Oc2c(F)c(F)c(F)c(F)c2F)c(F)c1F
InChI key
IOVVFSGCNWQFQT-UHFFFAOYSA-N
assay
97%
reaction suitability
reaction type: Carbonylations
mp
47-50 °C (lit.)
application(s)
peptide synthesis
functional group
carbonate
fluoro
Quality Level
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Application
双(五氟苯基)碳酸酯可用于制备：
- 一种名为6,6′-(乙烷-1,2-二基)双(1,3,6-二氧杂环辛-2-酮)的环状碳酸酯，是合成非异氰酸酯聚氨酯的关键中间体。
- 一种基于香豆素的脂肪族聚碳酸酯，名为5-(4-甲基伞形酮氧基羰基)-5-甲基-1,3-二氧己环-2-酮 (MUC)。
General description
双(五氟苯基)碳酸酯相当于羰基化合物，常用于偶联反应。它可用作氮杂肽制备试剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
[Dipentafluorophenylcarbonate in the synthesis of oligonucleotides by the H-phosphonate method].
V A Efimov et al.
Bioorganicheskaia khimiia, 20(3), 323-326 (1994-03-01)
Room temperature synthesis of non-isocyanate polyurethanes (NIPUs) using highly reactive N-substituted 8-membered cyclic carbonates
Yuen A, et al.
Polym. Chem., 7(11), 2105-2111 (2016)
Synthesis of cinnamoyl and coumarin functionalized aliphatic polycarbonates
Chesterman JP, et al.
Polym. Chem., 8(48), 7515-7528 (2017)
V N Medvedkin et al.
Bioorganicheskaia khimiia, 15(4), 460-464 (1989-04-01)
Dipentafluorophenylcarbonate, belonging to transesterifiying reagents, has been prepared and used for the synthesis of pentafluorophenyl esters of amino acids. In contrast to many other reagents of the kind, its preparation is simple, it is highly reactive and at the same
Bis(pentafluorophenyl)carbonate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2004)
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