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质量水平
检测方案
97%
反应适用性
reaction type: Carbonylations
mp
47-50 °C (lit.)
应用
peptide synthesis
SMILES字符串
Fc1c(F)c(F)c(OC(=O)Oc2c(F)c(F)c(F)c(F)c2F)c(F)c1F
InChI
1S/C13F10O3/c14-1-3(16)7(20)11(8(21)4(1)17)25-13(24)26-12-9(22)5(18)2(15)6(19)10(12)23
InChI key
IOVVFSGCNWQFQT-UHFFFAOYSA-N
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相关类别
一般描述
双(五氟苯基)碳酸酯相当于羰基化合物,常用于偶联反应。它可用作氮杂肽制备试剂。
应用
双(五氟苯基)碳酸酯可用于制备:
- 一种名为6,6′-(乙烷-1,2-二基)双(1,3,6-二氧杂环辛-2-酮)的环状碳酸酯,是合成非异氰酸酯聚氨酯的关键中间体。
- 一种基于香豆素的脂肪族聚碳酸酯,名为5-(4-甲基伞形酮氧基羰基)-5-甲基-1,3-二氧己环-2-酮 (MUC)。
WGK
WGK 3
闪点(°F)
230.0 °F
闪点(°C)
110 °C
个人防护装备
Eyeshields, Gloves, type N95 (US)
Bioorganicheskaia khimiia, 15(4), 460-464 (1989-04-01)
Dipentafluorophenylcarbonate, belonging to transesterifiying reagents, has been prepared and used for the synthesis of pentafluorophenyl esters of amino acids. In contrast to many other reagents of the kind, its preparation is simple, it is highly reactive and at the same
Room temperature synthesis of non-isocyanate polyurethanes (NIPUs) using highly reactive N-substituted 8-membered cyclic carbonates
Polym. Chem., 7(11), 2105-2111 (2016)
Synthesis of cinnamoyl and coumarin functionalized aliphatic polycarbonates
Polym. Chem., 8(48), 7515-7528 (2017)
Bis(pentafluorophenyl)carbonate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2004)
[Dipentafluorophenylcarbonate in the synthesis of oligonucleotides by the H-phosphonate method].
Bioorganicheskaia khimiia, 20(3), 323-326 (1994-03-01)
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