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质量水平
方案
97%
折射率
n20/D 1.4360 (lit.)
沸点
76-78 °C/20 mmHg (lit.)
密度
0.908 g/mL at 25 °C (lit.)
官能团
ether
ketal
SMILES字符串
CCOC1(CCCCC1)OCC
InChI
1S/C10H20O2/c1-3-11-10(12-4-2)8-6-5-7-9-10/h3-9H2,1-2H3
InChI key
MWUDABUKTZAZCX-UHFFFAOYSA-N
一般描述
环己酮二乙基缩酮（1,1-二乙氧基环己烷）与1,3,2-苯并二恶唑硼烷[儿茶酚硼烷（CB）]反应生成相应的醚。在气相中进行热消除反应，生成1-乙氧基环己烯和乙醇。
应用
环己酮二乙基缩酮可用于制备 1-乙氧基环己烯。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
140.0 °F
闪点(°C)
60 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Felix Rosas et al.
The journal of physical chemistry. A, 116(2), 846-854 (2011-12-22)
The gas-phase thermal elimination of 2,2-diethoxypropane was found to give ethanol, acetone, and ethylene, while 1,1-diethoxycyclohexane yielded 1-ethoxycyclohexene and ethanol. The kinetics determinations were carried out, with the reaction vessels deactivated with allyl bromide, and the presence of the free
Ozonolysis-reductive amination of olefins.
Pollart KA and Miller RE.
The Journal of Organic Chemistry, 27(7), 2392-2394 (1962)
Reactions of Enol Ethers with Carbenes. V. Rearrangements of Dihalocyclopropanes Derived from Six-, Seven-, and Eight-Membered Cyclic Enol Ethers1.
Parham WE, et al.
Journal of the American Chemical Society, 87(2), 321-328 (1965)
Catecholborane (1, 3, 2-benzodioxaborole). A versatile reducing agent.
Kabalka GW, et al.
The Journal of Organic Chemistry, 42(3), 512-517 (1977)
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