推荐产品
质量水平
检测方案
97%
折射率
n20/D 1.4360 (lit.)
bp
76-78 °C/20 mmHg (lit.)
密度
0.908 g/mL at 25 °C (lit.)
SMILES字符串
CCOC1(CCCCC1)OCC
InChI
1S/C10H20O2/c1-3-11-10(12-4-2)8-6-5-7-9-10/h3-9H2,1-2H3
InChI key
MWUDABUKTZAZCX-UHFFFAOYSA-N
一般描述
环己酮二乙基缩酮（1,1-二乙氧基环己烷）与1,3,2-苯并二恶唑硼烷[儿茶酚硼烷（CB）]反应生成相应的醚。在气相中进行热消除反应，生成1-乙氧基环己烯和乙醇。
应用
环己酮二乙基缩酮可用于制备 1-乙氧基环己烯。
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 2
闪点(°F)
140.0 °F
闪点(°C)
60 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Felix Rosas et al.
The journal of physical chemistry. A, 116(2), 846-854 (2011-12-22)
The gas-phase thermal elimination of 2,2-diethoxypropane was found to give ethanol, acetone, and ethylene, while 1,1-diethoxycyclohexane yielded 1-ethoxycyclohexene and ethanol. The kinetics determinations were carried out, with the reaction vessels deactivated with allyl bromide, and the presence of the free
Reactions of Enol Ethers with Carbenes. V. Rearrangements of Dihalocyclopropanes Derived from Six-, Seven-, and Eight-Membered Cyclic Enol Ethers1.
Parham WE, et al.
Journal of the American Chemical Society, 87(2), 321-328 (1965)
Catecholborane (1, 3, 2-benzodioxaborole). A versatile reducing agent.
Kabalka GW, et al.
The Journal of Organic Chemistry, 42(3), 512-517 (1977)
Ozonolysis-reductive amination of olefins.
Pollart KA and Miller RE.
The Journal of Organic Chemistry, 27(7), 2392-2394 (1962)
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