538329
N-乙酰乙酰苯胺
≥99.5%
别名:
1-(Phenylamino)-1,3-butanedione, 1-(Phenylcarbamoyl)-2-propanone, 3-Oxo-N-phenylbutanamide, 3-Oxo-N-phenylbutyramide, 4-(Phenylamino)-2,4-butanedione, Acetoacetamidobenzene
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所有图片(2)
About This Item
线性分子式:
CH3COCH2CONHC6H5
CAS号:
分子量:
177.20
Beilstein:
473419
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽密度
6.1 (vs air)
质量水平
方案
≥99.5%
自燃温度
843 °F
mp
83-88 °C (lit.)
官能团
amide
ketone
SMILES字符串
CC(=O)CC(=O)Nc1ccccc1
InChI
1S/C10H11NO2/c1-8(12)7-10(13)11-9-5-3-2-4-6-9/h2-6H,7H2,1H3,(H,11,13)
InChI key
DYRDKSSFIWVSNM-UHFFFAOYSA-N
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一般描述
Acetoacetanilide (N-phenyl-3-oxobutanamide) undergoes condensation reaction with o-phenylenediamine to afford a Schiff base. Dielectric constant of acetoacetanilide crystals were found to increase on exposure to 120MeV Ag13+ ions due to increase in number of defects. Acetoacetanilide/Ce4+ system serves as an initiator during the polymerization of vinyl monomers.
应用
Acetoacetanilide may be used to synthesize:
- azo pigments
- acetoacetanilido-4-aminoantipyrine (Schiff base)
- 6-aryl-2-methyl-4-oxo-N,N′-diphenyl-2-cyclohexene-1,3-dicarboxamides
- photoluminescent lanthanide complexes
储存分类代码
11 - Combustible Solids
WGK
WGK 3
法规信息
新产品
Synthesis and photoluminescent properties of lanthanides acetoacetanilide complexes
Souza, E. R., et al.
Journal of Fluorescence, 23.5, 939-946 (2013)
Crystal structures of azo pigments derived from acetoacetanilide
Whitaker, A.
Journal of the Society of Dyers and Colourists, 104.7-8 , 294-300 (1988)
On the kinetics and initiation mechanism of acrylamide polymerization using the ceric ion/acetoacetanilide system as initiator
Dong JH, et al.
Macromolecular Chemistry and Physics, 195.3, 823-831 (1994)
Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and VO (II) Schiff base complexes derived fromo-phenylenediamine and acetoacetanilide
Raman N, et al.
Journal of Chemical Sciences (Bangalore), 113.3 , 183-189 (2001)
Effect of swift heavy ion (SHI) irradiation on dielectric properties of acetoacetanilide crystals
Prabhu SG, et al.
Nuclear Instruments & Methods in Physics Research. Section B, Beam Interactions With Materials and Atoms null
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