推荐产品
质量水平
产品线
ReagentPlus®
方案
≥98.5% (GC)
自燃温度
536 °F
制造商/商品名称
Sigma-Aldrich
折射率
n20/D 1.419 (lit.)
沸点
169-170 °C/70 mmHg (lit.)
mp
−80 °C (lit.)
密度
1.076 g/mL at 25 °C (lit.)
官能团
ester
ketone
SMILES字符串
COC(=O)CC(C)=O
InChI
1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3
InChI key
WRQNANDWMGAFTP-UHFFFAOYSA-N
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应用
乙酰乙酸甲酯（MAA）可用作以下反应的反应物：
- 通过使用各种催化剂与醇进行酯交换反应
- 在锌和 I2 作为催化剂的条件下，由苯酚合成4-甲基香豆素
- 用过渡金属作为催化剂，进行不对称多相加氢反应。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1
储存分类代码
10 - Combustible liquids
WGK
WGK 1
闪点(°F)
158.0 °F - closed cup
闪点(°C)
70 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Zinc mediated transesterification of ?-ketoesters and coumarin synthesis.
Chavan SP, et al.
Tetrahedron Letters, 43(47), 8583-8586 (2002)
Synthesis and studies of 6, 6′ -BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate.
Saluzzo C, et al.
Tetrahedron Asymmetry, 13(11), 1141-1146 (2002)
Synergism between microwave and enzyme catalysis in intensification of reactions and selectivities: transesterification of methyl acetoacetate with alcohols.
Yadav GD and Lathi PS
J. Mol. Catal. A: Chem., 223(1-2), 51-56 (2004)
Enantioselective hydrogenation of methyl acetoacetate catalyzed by nickel supported on activated carbon or graphite.
Wolfson A, et al.
Applied Catalysis A: General, 208(1-2), 91-98 (2001)
Xiao Hu et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(47), 16796-16801 (2014-11-05)
Much remains unknown regarding speciation. Host-pathogen interactions are a major driving force for diversification, but the genomic basis for speciation and host shifting remains unclear. The fungal genus Metarhizium contains species ranging from specialists with very narrow host ranges to
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