生物来源
Pseudomonas fluorescens
质量水平
比活
≥20,000 U/g, pH 8.0, 55 °C (Optimum pH and temperature)
≥20,000 U/g
颜色
beige-brown
InChI
1S/C11H9N3O2.Na/c15-8-4-5-9(10(16)7-8)13-14-11-3-1-2-6-12-11;/h1-7,16H,(H,12,14);/q;+1/b13-9-;
InChI key
QWZUIMCIEOCSJF-CHHCPSLASA-N
应用
来自 荧光假单胞菌 的天野脂肪酶可用作以下反应的生物催化剂：
天野脂肪酶也可在蚕丝蛋白上固定，从而通过卤代醇的酶动力学拆分制备具备光学活性的环氧化物。
- 对羟基苯甲酸酯的水解和酯交换。
- 氯醇的酶动力学拆分。
- 以不同酰化剂进行穿心莲内酯的区域选择性酰化，以合成穿心莲内酯衍生物。
天野脂肪酶也可在蚕丝蛋白上固定，从而通过卤代醇的酶动力学拆分制备具备光学活性的环氧化物。
警示用语：
Danger
危险声明
预防措施声明
危险分类
Resp. Sens. 1
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
常规特殊物品
Immobilization of Amano lipase from Pseudomonas fluorescens on silk fibroin spheres: an alternative protocol for the enantioselective synthesis of halohydrins
Ferreira IM, et al.
Royal Society of Chemistry Advances, 7(21), 12650-12658 (2017)
Lei Wang et al.
Journal of hazardous materials, 354, 145-152 (2018-05-12)
Hydrolysis is generally considered as the main pathway for the degradation of ester-type pollutants in aquatic environments. In this study, we found that when methanol or ethanol presented as the external carbon in the activated sludge, transesterification is very important
Lipase catalyzed synthesis of antimicrobial andrographolide derivatives
Patil Harshal S, et al.
Data in Brief, 18, 1134-1141 (2018)
Highly enantioselective acylation of chlorohydrins using Amano AK lipase from P. fluorescens immobilized on silk fibroin-alginate spheres
Ferreira IM, et al.
Tetrahedron Letters, 55(36), 5062-5065 (2014)
Dominik Koszelewski et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(43), 10156-10164 (2019-05-29)
A new protocol based on lipase-catalyzed tandem reaction toward α,β-enones/enoesters is presented. For the synthesis of the desired products the tandem process based on enzyme-catalyzed hydrolysis and Knoevenagel reaction starting from enol acetates and aldehyde is developed. The relevant impact
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