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检测方案
97%
折射率
n20/D 1.47 (lit.)
bp
140-141 °C (lit.)
密度
1.077 g/mL at 25 °C (lit.)
SMILES字符串
Cc1cccc(F)n1
InChI
1S/C6H6FN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3
InChI key
UDMNVTJFUISBFD-UHFFFAOYSA-N
一般描述
2-Fluoro-6-methylpyridine, also known as 2-fluoro-6-picoline, can be prepared via diazotization of 2-amino-6-methylpyridine in hydrogen fluoride containing 40% pyridine solution. The effect of substituents on spectral properties of 2-fluoro-6-methylpyridine has been investigated based on 13C NMR, UV and IR spectral data.
应用
2-Fluoro-6-methylpyridine may be used in the preparation of:
- 2-fluoro-6-pyridinecarboxylic acid
- 2,2′-[1-(6-methylpyridin-2-yl)ethane-1,1-diyl]dipyridine
- 2-fluoropyridine-6-aldoxime
- 2-fluoro-6-(dibromomethyl)pyridine
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Efficient synthesis of pentakis-and tris (pyridine) ligands.
Unal EA, et al.
Tetrahedron Letters, 53(1), 54-55 (2012)
Synthesis of some fluorine-containing pyridinealdoximes of potential use for the treatment of organophosphorus nerve-agent poisoning.
Timperley CM, et al.
Journal of Fluorine Chemistry, 132(8), 541-547 (2011)
A facile preparation of fluoropyridines from aminopyridines via diazotization and fluorodediazoniation in HF or HF-pyridine solutions.
Fukuhara T, et al.
Journal of Fluorine Chemistry, 38(3), 435-438 (1988)
The synthesis of 2-fluoro-4-and 2-fluoro-6-pyridinecarboxylic acid and derivatives.
Roe A, et al.
Journal of the American Chemical Society, 71(12), 4152-4153 (1949)
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